Novel Cerium(III)-(R)-BNP Complex as a Storable Chiral Lewis Acid Catalyst for the Enantioselective Hetero-Diels-Alder Reaction

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概要

• 論文の詳細を見る
• 2003-07-05

著者

• OHBA Masaaki

  Department of Chemistry, Graduate School of Science, Kyushu University

• OKAWA Hisashi

  Department of Chemistry, Graduate School of Science, Kyushu University

• Okawa Hisashi

  Department Of Chemistry Faculty Of Science Kyushu University

• HAYANO Tetsuji

  Institute for Materials Chemistry and Engineering (IMCE), Kyushu University

• SAKAGUCHI Toshiaki

  Institute for Materials Chemistry and Engineering (IMCE), Kyushu University

• FURUNO Hiroshi

  Institute for Materials Chemistry and Engineering (IMCE), Kyushu University

• INANAGA Junji

  Institute for Materials Chemistry and Engineering (IMCE), Kyushu University

• Ohba Masaaki

  Department Of Chemistry Faculty Of Science Kyushu University

• Inanaga Junji

  Institute For Materials Chemistry And Engineering (imce) Kyushu University

• Inanaga Junji

  Institute For Fundamental Research Of Organic Chemistry (ifoc) Kyushu University

• Furuno Hiroshi

  Institute For Materials Chemistry And Engineering (imce) Kyushu University

• Hayano Tetsuji

  Institute For Materials Chemistry And Engineering (imce) Kyushu University

• Okawa Hisashi

  Department Of Chemistry Faculty Of Sciences Kyushu University

• Ohba Masaaki

  Department Of Architecture Faculty Of Engineering Tokyo Institute Of Polytechnics

• Ohba Masaaki

  Department Of Chemistry Faculty Of Sciences Kyushu University

• Sakaguchi Toshiaki

  Institute For Materials Chemistry And Engineering (imce) Kyushu University

関連論文

• Synthesis and Redox Behavior of Dicobalt Complexes Having Flexible and Rigid Linkers
• Synthesis and Electrochemical Properties of Tetranuclear Di-μ-oxo-bis[di-μ-phenolatodiiron(III)] Complexes
• Dinuclear Mn(II), Ni(II), and Zn(II) Complexes Bridged by Bis(p-nitrophenyl) Phosphate Ion : Relevance to Bimetallic Phosphodiesterase
• μ-Acetato-di-μ-phenolato-metal(II)cobalt(II) (Metal = Fe, Co, Ni, Cu, Zn) Complexes with Low-Spin Co(II) : Synthesis, Structures, and Magnetism
• Novel Cerium(III)-(R)-BNP Complex as a Storable Chiral Lewis Acid Catalyst for the Enantioselective Hetero-Diels-Alder Reaction
• Synthesis, Structure and Magnetic Property of a Tetranuclear Iron(III) Complex of "Face-to-Face" Type
• Synthesis and Structures of Novel Discrete Ni(II)-Ln(III) Heterodinuclear Complexes (Ln=Gd or Lu)
• A Novel Discrete d-f Heterobinuclear Complex Designed from Tetrahedrally Distorted [Cu (salabza)] (H_2salabza : N,N'-Bis (salicylidene)-2-aminobenzylamine) and [Gd (hfac)_3]
• Copper(II)-Lanthanide(III) Complexes of Symmetric Dinucleating Macrocycle with Two Phenolate Bridges
• Heat Capacity of a Layered Molecule-Based Ferrimagnet [Mn^(S-pnH)(H_2O)][Mn^(CN)_6]・2H_2O
• Magnetic Excitation in Artificially Designed Oxygen Molecule Magnet(Condensed matter: electronic structure and electrical, magnetic, and optical properties)
• Valence States and Structure of Mixed-Valence Dinuclear Iron(II,III) Complexes [Fe_2(2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-menthyl-phenol)(L)_2](BF_4)_2
• Characterization of a Fluoride-bridged Mixed-valent Tetrairon(II,II,III,III) Complex
• Structures of Bimetallic Assemblies Derived from a Macrocyclic Dinuclear Copper(II) Complex and [Cr(ox)3]〔3-〕 or [Co(CN)6]〔3-〕
• Electrochemical Studies for Interaction between [Cu(salen)] and La(III) Ion in N,N-Dimethylformamide
• New Pyridine-modified Macrocycle and Its Ability to Encapsulate Four Divalent Metal Ions [Nickel(II), Manganese(II), and Zinc(II)] into the Ring
• Di(phenoxo)-bridged Dinuclear Mn_2(II,II) and Mn_2(II,III) Complexes of Macrocyclic Ligands : Structure, Properties, and Catalase-Like Function :
• Template Synthesis and Structure of a Dilead(II) Complex of a Macrocycle with N_8O_2 Donor Set
• Dinuclear Copper(II) Complexes of a Macrocyclic Compartmental Ligand in Two Isomeric Forms. Exogenous Ion Effect upon Ligand Isomerism
• Synthesis of a Tetracopper Assembly Complex Comprised of One Macrocyclic Dinuclear Copper Unit and Two Mononuclear Copper Units : Intramolecular Electron Transfer Relevant to Multicopper Oxidase
• Macrocyclic Heterodinuclear Co^M^ (M = Ni, Zn) Complexes. Ferromagnetic Interaction and EPR of Co^Ni (S_ = 1/2, S_ = 1) Complex
• Tetranuclear Ni^ and Dinuclear Mn^ Complexes Derived from a New Macrocyclic Ligand with Four Endogenous Phenolic Groups
• Hydrolytic Activity of A Fe^Zn^ Complex toward Di(p-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiestelase
• μ-Hydroxo-μ-phenolato Dinuclear Zinc(II) and Nickel(II) Complexes Derived from Dinucleating Compartmental Ligands of "End-off" Type : Synthesis, Structures, and Properties
• Template Synthesis of Copper Complexes of Dinucleating and Tetranucleating Macrocyclic Ligands
• Hydrolytic Activity of Zn^Zn^ and Zn^Ba^ Complexes toward Tri (p-nitrophenyl) Phosphate and Di (p-nitrophenyl) Phosphate: A Functional Model of Heterobimetallic Phosphodiesterase
• Copper(II) Compounds Extended by 5-Carboxysalicylaldehyde and Its Schiff Bases: Interplay of Two Metal-Binding Sites and Intermolecular Stacking Contributing to Their Network and Bulk Structures
• Synthesis and Characterization of Triple-decker Sandwich Dinuclear La(III)and Lu(III)Complexes of 2, 3, 9, 10, 16, 17, 23, 24-Octabutoxyphthalocyanine
• Syntheses and Structural Characterization of Dinuclear and Trinuclear Iron(II) Complexes of Tridentate Thiolic Ligands with an NNS Donor Set
• Metal-Complex Ferrimagnets with the Formula {NBu_4[M(II)Fe(III)(ox)_3]}_(NBu_4^+=Tetra(n-butyl)ammonium Ion, ox^=Oxalate Ion, M=Fe^, Ni^)
• Structures and Dielectric Properties in Thermochromic Nickel(II) Compounds
• Synthesis and Characterization of a Tetrahedral and Octahedral Cobalt(II) Alternate Chain Complex
• Magneto-optical Properties of Two-dimensional Cyanide-Bridged M^Ni^ Bimetallic Assemblies (M=Fe,Co)
• A Bimetallic Magnetic System Exhibiting Reversible Ferromagnetism/Metamagnetism Modulation
• Structures and Magnetism of Cyanide-Bridged Bimetallic Compounds : Design of Complex-Based Magnetic Materials
• A Rare μ_3η^1, η^2 Perolxo Bridge between Two Co^Pb^ Dinuclear Units and Hydrolytic Conversion into a Hydroxo-Bridged Co^Pb^ Complex
• Hydrolytic Function of a Hydroxo-Zn^Pb^ Complex toward Tris-p-nitrophenyl Phosphate:A Functional Model of Heterobimetallic Phosphatases
• Three-dimensional Ferromagnetic Frameworks of Syn-Anti-type Carboxylate-bridged Ni^ and Co^ Coordination Polymers
• Heterodinuclear M^Ni^ (M = Co, Ni, Cu, Zn) Complexes of a Macrocyclic Compartmental Ligand. Anomalous EPR of Cu^Ni^ Complex by Coordination of 1-Methylimidazole
• A Geometrically Asymmetric Dinuclear Copper(II) Complex Derived from A New Unsymmetric 'End-off' Compartmental Ligand
• Template Synthesis of Phenol-based Heterodinucleating Macrocycles with Dissimilar N(amine)_2O_2 and N(imine)_2O_2 Metal-binding Sites
• Scandium(III) Perfluorooctanesulfonate [Sc(OPf)_3]: A Novel Catalyst for the Hetero Diels-Alder Reaction of Aldehydes with Non-Activated Dienes
• YTTERBIUM(III) PERCHLORATE AS A CATALYTICPROMOTER OF THE GLYCOSYLATION OF l-O-METHOXYACETYLSUGARS WITH ALCOHOLS
• Reversible Oxygenation of a μ-Acetato-di (μ-phenoxo) dicobalt (II) Core Complex and Crystal Structure of Its Oxygenated Complex
• Dinuclear Zinc Complexes of Phenol-Based "End-off" Compartmental Ligands: Synthesis, Structures and Phosphatase-Like Activity
• Magnetic Susceptibility of Some Mixed-Metal Compounds : NBu_4Zn(II)_xFe(II)_[Fe(III)(ox)_3]
• Isomerization of a Linear Pentamine, 1,4,7,10,13-Pentaazatridecane, to a Branched Form, 4-(Aminoethyl)-1,4,7,10-tetraazadecane, on a Schiff-base Copper Complex Relevant to Multi-copper Enzymes
• Synthesis and Ferromagnetic Spin-Coupling of Imidazolate-Bridged 3d-4d Cu(II)-Ru(III) Binuclear Complex
• Template Synthesis of Masrocyclic Dinuclear Cu^ Complexes and Conversion into Mononuclear Complexes by Site-Selective Copper Elimination
• A Macrocyclic Co(II)Pb(II)Complex : Neighboring Pb(II)Effect upon Reversible Superoxo-cobalt Complex Formation in Solid State
• Dioxygen Oxidation of Coordinated Nitrosyl to Nitro on Dmf-Bridged Dinuclear CoPb Complex
• Crystal structure of (chloro(tris((1-ethyl-1H-benzimidazol-2-yl)-methyl)amine)zinc(II)) tetraphenylborate acetone.
• Crystal structure and magnetic property of cubane tetranuclear copper(II) complex with ferromagnetic coupling.
• Specific binding of substrates containing nitrogen and oxygen donor groups to copper(II)-gadolinium(III) hetero-metal center.
• Crystal and molecular structure of a binuclear copper(II) complex with 1,2,3,4-tetrakis(salicylideneamino)-2,3-dimethylbutane.
• Binuclear metal complexes. XLIII. Magnetic, spectroscopic, and electrochemical studies on hetero-metal binuclear complexes of N,N'-bis(3-carboxysalicylidene)-1,1-dibenzylethylenediamine.
• Catalytic function of cobalt(III) complexes with N,N'-disalicyl-ideneethylenediamine on oxygenation of t-butylphenols.
• Synthesis and characterization of a chloro-bridged binuclear iron(III) complex.
• Ferromagnetic Spin-Coupling between Gadolinium(III) and Copper(II) Ions in Discrete Binuclear Gd(III)-Cu(II) Complexes.
• Nocovalent interactions in metal complexes. 14 Proton NMR spectroscopic investigation on stereoselectivity in cobalt(III) complexes of various 3-substituted 1-phenyl-1,3-propanediones.
• Binuclear Metal Complexes. X. Preparation and Magnetism of Mononuclear and Binuclear Copper(II) Complexes of Schiff Bases Derived from 4,6-Diacetylresorcine and Polyamines
• Noncovalent interactions in metal complexes. VIII. Syntheses, properties, and stereoselectivities of lanthanoid complexes with 1-l-menthyloxy-3-benzoylacetone.
• Binuclear metal complexes. LI. Synthesis and characterization of the tetrachloro-o-benzoquinone adducts of binuclear iron(II) complexes with 2-(salicylideneamino)phenol and its substituted homologs.
• Synthesis and magnetic property of binuclear oxovanadium(IV) complex of 2,6-diformyl-4-methylphenol bis(benzoylhydrazone).
• Synthesis and characterization of a new quinquedentate ligand consisting of salen skeleton and phenolic tail capable of axial coordination and its metal complexes.
• Binuclear metal complexes. 58 Synthesis and properties of mixed-valence diiron(III,IV) complexes of salen analogs with pendant thioether group.
• High stereoselectivity of tris(4-(l-menthyloxy)-1-(p-tolyl)-1,3-butandionato)lanthanoid(III).
• Binuclear metal complexes. XXIV. Synthesis and magnetism of binuclear cobalt(II) complexes in mixed-spin state.
• Binuclear metal complexes. XXXI. Synthesis and magnetic property of binuclear manganese (III) complexes with 3-salicylideneamino-1-propanol and its homologues.
• Binuclear metal complexes. XLII. Manganese(IV) complexes synthesized by oxidation of binuclear manganese(II) complexes of 2-(salicylideneamino)phenols with tetrachloro-o-benzoquinone.
• Binuclear metal complexes. XLV. Synthesis and magnetic, spectral, and electrochemical studies of strati-bis copper(II) complexes of some Schiff bases derived from primary tetraamines and salicylaldehydes.
• Binuclear metal complexes. IL. Synthesis, ESR, and electrochemical properties of strati-bis copper(II)-nickel(II) complexes.
• Macro Chelate Rings. III. Syntheses and Configurations of Complexes of New Ligands, 4,4′-Dimethyl-2,2′-bis(salicylideneaminomethyl)-diphenyl Ether and 4,4′-Dimethyl-2,2′-bis(salicylideneaminomethyl)diphenylamine
• Macro Chelate Rings. II. Syntheses and Properties of 2,7-Dimethyl-4,5-bis(salicylideneaminomethyl)xanthone as a Quadridentate Chelating Agent and Its Metal Complexes
• Binuclear Metal Complexes. IX. Syntheses and Magnetic Properties of Copper(II) and Nickel(II) Complexes of Schiff Bases Derived from 3-Formylsalicylic Acid and Alkyl Amines
• Binuclear metal complexes. XXIII. Molecular structure of a hetero-metal binuclear complex, CuCo(fsaen) 3H2O(C18H18N2O9CoCu).
• Substituent effect on stereoselectivity for cobalt(III), chromium(III), and manganese(III) complexes of ring-substituted 1-l-menthyloxy-3-benzoylacetones.
• Synthesis, spectral and magnetic properties and crystal structures of alkoxo-oxygen coordinated copper(II) complexes of N,N'-disubstituted malonamide and oxamide derivatives.
• Binuclear Metal Complexes. XIII. Syntheses and Magnetic Properties of Thiocyanato-Bridged Binuclear Copper(II) Complexes
• Synthesis and characterization of copper(II) and nikel(II) complexes of 1,5-diamino-3-pentanol and its derivatives.
• Stereoselectivity in Diastereomeric Tetrahedral Metal(II) Complexes of Chiral Salicylideneamines: Crystal Structure and Molecular Mechanics Calculation of Bis(N-(l-menthyl)salicylideneaminato)cobalt(II).
• Copper(II)-lanthanoid(III) complexes of binucleating ligands derived from 3-formylsalicylic acid and diamines.
• Binuclear metal complexes. XXXIX. Synthesis and properties of binuclear copper(II) complexes with (2-(2-pyridyl)ethylamino)-alkanols and (2-(2-pyridyl)ethylthio)alkanols.
• Binuclear metal complexes. XLI. Crystal structure and unusual magnetic property of isothiocyanato{2-(2-(dimethylamino)ethylthio)ethanolato}copper(II).
• Antiferromagnetic spin-exchange interaction in mixed-spin trinuclear cobalt(II) complexes with quadridentate schiff bases.
• Non-covalent interactions in metal complexes. II. Induction of asymmetry in cobalt(III) complexes with amino acid-schiff bases. Importance of CH .PI.-interaction in determining configuration of complexes.
• Synthesis and magnetism of trinuclear copper(II) complexes with a salen-like Schiff base and a tertiary diamine.
• Copper(II)-Rare Earth(III)(Ln=La,Gd,Lu) Binuclear Complexes of Bis(2-(3-carboxysalicylidene)aminoethyl)amine: Characterization and Specific Binding of Amino Alcohols.
• Binuclear metal complexes. XLIV. Crystal structures and magnetic properties of alkoxo-oxygen bridged binuclear copper(II) complexes with 2-(2-(dialkylamino)ethylthio)ethanol.
• Syntheses and configurations of copper(II) and nickel(II) complexes of trans-1,2-dicyano-1,2-cyclohexanediamine.
• Template synthesis and crystal structure of a dilead(II) complex of a macrocycle with N4O2 donor set.
• Synthesis and characterization of imidazolate-bridged copper(II) complexes of triangular skeleton.
• Synthesis, magnetic property, and crystal structure of imidazolate-bridged manganese(III)-copper(II) dinuclear complex.
• Binuclear Metal Complexes. XI. Substituent Effect upon Magnetisms of Binuclear Oxovanadium(IV) and Copper(II) Complexes of the Schiff Bases, 2,6-Bis[N-(2-hydroxy-5-substituted-phenyl)iminomethyl]-4-methylphenol
• Binuclear metal complexes XXXV. Synthesis and magnetism of binuclear copper(II) complexes with 3-(2-(dialkylamino)ethylthio)-1-propanols.
• Binuclear Copper(II) Complexes Derived From 3-Formyl-5-methyIsaIicyIaldehyde and Glycine
• Binuclear Metal Complexes. VII. Preparation and Properties of Binuclear Copper(II) and Nickel(II) Complexes of Hydrogen-bridged Macrocycles
• Binuclear Metal Complexes. III. Preparation and Properties of Mononuclear and Binuclear Copper(II) and Nickel(II) Complexes of New Macrocycles and Their Related Ligands
• Binuclear metal complexes. XXXVII. Crystal and molecular structure of a binuclear manganese(III) complex bridged by two alkoxo oxygens and two bidentate acetate ions.
• Dinuclear cobalt(II), iron(II), and manganese(II), and trinuclear manganese(II) complexes with tridentate ligands of NNS-donor set derived from 2-aminoethanethiol.

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