Binuclear metal complexes. XXXVII. Crystal and molecular structure of a binuclear manganese(III) complex bridged by two alkoxo oxygens and two bidentate acetate ions.
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The crystal structure of binuclear manganese(III) complex, Mn(spa)(ac) (H<SUB>2</SUB>spa=3-salicylideneamino-1-propanol, ac=acetate), was determined by the single-crystal X-ray diffraction method. The crystals are triclinic, space group P\bar1, <I>a</I>=8.804(3), <I>b</I>=9.376(3), <I>c</I>=8.671(3) Å, α=111.24(3), β=101.34(3), γ=65.00(3)°, and <I>Z</I>=1. The structure was solved by the heavy atom method and refined by the block-diagonal least-squares method to an <I>R</I> factor of 0.034. The crystal structure consists of discrete binuclear clusters, where the two manganese atoms are bridged by two alkoxo oxygens of the spa ligands and two bidentate acetate ions. The structural detail is in conformity with the magnetic and spectral properties previously reported.
- 公益社団法人 日本化学会の論文
著者
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Okawa Hisashi
Department Of Chemistry Faculty Of Science Kyushu University
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Mikuriya Masahiro
Department Of Chemistry And Open Research Center For Coordination Molecule-based Devices School Of S
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Kida Sigeo
Department of Chemistry Wakayama University
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Torihara Naoyuki
Department of Chemistry, Faculty of Science, Kyushu University
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Mikuriya Masahiro
Department of Chemistry, Faculty of Science, Kyushu University 33
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