X-ray crystal structure and electrochemical property of a novel monohydroxo-bridged binuclear cobalt(II) complex with N,N',N",N'"-tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane.

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概要

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• The crystal structure of a binuclear cobalt(II) complex of <I>N</I>,<I>N</I>′,<I>N</I>″,<I>N</I>'″-tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane (taec), [Co<SUB>2</SUB>(taec)(OH)](ClO<SUB>4</SUB>)<SUB>3</SUB>, was determined by the single-crystal X-ray diffraction method. The two cobalt ions are bridged by a single hydroxide ion in the cavity of taec. The cyclic voltammogram showed an irreversible profile with two anodic peaks at ca. 1.4 and 1.8 V vs. SCE.

• 公益社団法人 日本化学会の論文

著者

• Mikuriya Masahiro

  Department Of Chemistry And Open Research Center For Coordination Molecule-based Devices School Of S

• Kida Sigeo

  Department of Chemistry Wakayama University

• MIKURIYA Masahiro

  Department of Chemistry, School of Science, Kwansei Gakuin University

• Kohzuma Takamitsu

  Coordination Chemistry Laboratories, Institute for Molecular Science

• Murase Ichiro

  Laboratory of Chemistry, College of General Education, Kyushu University 01

• Murase Ichiro

  Laboratory of Chemistry, College of General Education, Kyushu University

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