Novel Tetranuclear Nicke(II) Complex with a Mixed-Spin State Generated by Pairing of Dimers

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概要

• 論文の詳細を見る
• 1993-04-05

著者

• KOTERA Takanori

  Department of Chemistry, School of Science, Kwansei Gakuin University

• Kotera T

  Kwansei Gakuin Univ. Sanda

• Kotera Takanori

  Department Of Chemistry And Open Research Center For Coordination Molecule-based Devices School Of S

• Mikuriya M

  Department Of Chemistry School Of Science And Technology Kwansei Gakuin University

• Mikuriya Masahiro

  Department Of Chemistry And Open Research Center For Coordination Molecule-based Devices School Of S

• NAKADERA Keiichi

  Department of Chemistry, School of Science, Kwansei Gakuin University

• Nakadera K

  Department Of Chemistry School Of Science Kwansei Gakuin University

• Nakadera Keiichi

  Department Of Chemistry School Of Science Kwansei Gakuin University

関連論文

• Polymer Complexes of Rhodium(II) Trifluoroacetamidate with Pyrazine, 4,4'-Bipyridine, and 1,4-Diazabicy-clo[2.2.2]octane
• Dinuclear Copper(II) Complexes of Free Radical Carboxylic Acids
• Antiferromagnetic Adducts of Copper(II) Propionate with Pyridyl Nitronyl Nitroxides
• Adduct Polymers and Dimers of Rhodium(II) Pivalate with Pyrazine, 4, 4'-Bipyridine, 1, 4-Diazabicyclo[2. 2. 2]octane, Triethylamine, and Pyridine
• Synthesis, X-Ray Structures, and Magnetic Properties of [Cu_2(piv)_4(Et_3N)_2] and [Cu_6(piv)_6(EtO)_6] (Hpiv = Pivalic Acid ) : Role of Base for Dinuclear Adduct and Oligonuclear Formation
• Self-assembly of Mixed-valent Ruthenium(II, III) Pivalate and Octacyanotungstate(V) Building Blocks
• A Polymer Complex [Cu(O_2CC_6F_5)_2-(pyz)]_n Formed from Copper(II) Pentafluorobenzoate and Pyrazine
• Synthesis and Characterization of Polynuclear Chain and Tetranuclear Complexes of Mixed-Valent Ruthenium(II, III) Pivalate with N, N'-Didentate Ligands
• Polymer and "Trimer-of-Dimers" Complexes Derived from [Rh_2(form)_4] (form^-=N, N'-Di-p-tolylformamidinate anion) and 1, 4-Diisocyanobenzene
• Syntheses and Magnetic Properties of Ruthenium(II, III) Pivalate Dimers Axially Coordinated by Nitronyl Nitroxide Radicals [Ru_2(O_2CCMe_3)_4-(L)_2]BF_4 and [{Ru_2(O_2CCMe_3)_4(L)_2}{Ru_2(O_2CCMe_3)_4(H_2O)_2}]_n(BF_4)_, L=2, 4, 4, 5, 5-Pentamethyl-4,
• Molecular-assembled Complexes of Mixed-valent Ruthenium Dimer with Hexacyanoferrate(III) and Hexacyanocobaltate(III) Ions
• Structure and Magnetic Properth of Ru(II,III) Dimer Axially Coordinated by the Niroxide Radical and Water [Ru_2(O_2CCMe_3)_4(nitph)(H_2O)]BF_4,nitph = 2-Phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide
• Structure and Magnetic Property of a Macrocyclic Tetranuclear Copper(II) Complex with Phenoxo- and Hydroxo-Bridges and Large and Small Cu-O-Cu Angles
• Structures and Magnetic Properties of Ruthenium(II, III) Pivalate Cation Dimers Axially Coordinated by Pyridyl Nitronyl Nitroxide Radicals through Their Pyridyl Nitrogen Atoms
• Synthesis and Structural Characterization of Thiolato-Bridged Zinc(II) Complexes with NNS-Tridentate Thiolic Ligands
• New Pyridine-modified Macrocycle and Its Ability to Encapsulate Four Divalent Metal Ions [Nickel(II), Manganese(II), and Zinc(II)] into the Ring
• A New "Dimer-of-Dimers" Complex Derived from Axial Coordination of 7, 7, 8, 8-Tetracyanoquinodimethane to Ru(II, III)Cation Dimer
• Chain Compound of Mixed - Valent Ruthenium Dimers Linked by Hydrogen - Bonding between the Axially Coordinated Nitronyl Nitroxide and Water Molecules
• Microporous Structure of a Chain Compound of Copper(II) Benzoate Bridged by Pyrazine
• Chain Compounds of Molybdenum(II) Trifluoroacetate Linked by p-Quinones [Mo_2(O_2CCF_3)_4(p-quin)]_n, p-quin = 9,10-anthraquinone, 2,6-dimethyl-1,4-benzoquinone, and 1,4-naphthoquinone
• Ferromagnetic Chain Complex of Ruthenium (II, III) Pivalate with Pyridy Nitronyl Nitroxide
• Structure and Magnetic Properties of a Chain Complex with Alternating Ru(II,III) Dimer and Nitroxide Radical Arrangement [Ru_2(O_2CCMe_3)_4(nitph)]_n(BF_4)_n, nitph = 2-Phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-N-Oxide
• Synthesis and Characterization of Thiolato-Bridged Trinuclear Heterometal Complexes with 2-[(3-Aminopropyl)amino]ethanethiol
• Chain Compounds of Rhodium(II) Trifluoroacetate Linked by p-Quinone Rh_2(O_2CCF_3)_4(p-Q)]_n, p-Q=1, 4-Benzoquinone, 1, 4-Naphthoquinone, and 2, 3-Dimethy1-1, 4-benzoquinone
• A Chain Complex of Ruthenium (II, III) Cation Dimer Linked by a Nitroxide Radical, [Ru_2 (O_2CCMe_3) _4 (NITPh)] _n (BF_4) _n (NITPh=2-Phenyl-4, 4, 5, 5-tetramethyl-4, 5-dihydro-1H-imidazolyl-1-oxy-3-oxide)
• Chain and Discrete Dimer Complexes of Molybdenum(II) Trifluoroacetate Axially Coordinated by p-Quinones, [Mo_2(O_2CCF_3)_4(2,6-Me-BQ]_n(2,6-Me-BQ=2,6-dimethyl-p-benzoquinone)and [Mo_2(O_2CCF_3)_4(2,6-t-Bu-BQ)_2 (2,6-t-Bu-BQ=2,6-di-t-butyl-p-benzoquinone)
• Linear Chain Compounds of Molybdenum(II) Acetate Linked by Phyrazine, 4,4'-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane
• Chain Compounds Formed by the Reaction of Copper(II) Carboxylate [Cu_2(O_2CR)_4] (R = C(CH_3)_3CCl_3 and Bridging Ligand L (L = Pyrazine, 4,4'-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane)
• Structure and Magnetic Properties of a Nitroxide Diruthenium(II,III) Complex, [Ru_2(O_2CCMe_3)_4(tempo)_2] {Ru_2(O_2CCMe_3)_4(H_2O)_2](BF_4)_2(tempo=2,2,6,6,-Tetramethylpiperidine-1-oxyl)
• Syntheses and Structural Characterization of Dinuclear and Trinuclear Iron(II) Complexes of Tridentate Thiolic Ligands with an NNS Donor Set
• Structure and Properties of a Compound Formed by the Reaction of Molybdenum(II) Trifluoroacetate with 4,4'-Bipyridine
• A Novel Chain Compound Composed of Rhodium(II) Pivalate Dimer and 1,4-Benzoquinone
• Structural Characterization and Magnetic Properties of Triply Carboxylato-Bridged Dinuclear Copper(II) Complexes
• Synthesis and Structural Characterization of Thiolato-Bridged Tetranuclear Palladium(II) Complexes with N,N,S-Tridentate Ligands
• Synthesis and Structural Characterization of Tetranuclear Zinc(II) Complexes with a Linear Array
• One-Dimensional Coordination Polymers from the Self-Assembly of Copper(II) Carboxylates and 4, 4'-Dithiobis(pyridine)
• Synthesis, Crystal Structures, and Magnetic Properties of Dinuclear and Hexanuclear Copper(II) Complexes with Cyclam-Based Macrocyclic Ligands Having Four Schiff-Base Pendant Arms
• Isolation of a Unique Hexanuclear [Bi_6O_4OH(cit)_3(H_2O)_3]^ Cluster from the Bismuth-Containing Ulcer Healing Agent "Colloidal Bismuth Subcitrate (CBS)"
• Dinuclear Manganese(III) Complex with Cyclam-based Dodecadentate Ligand Bearing Schiff-base Pendants (Cyclam = 1, 4, 8, 11-Tetraazacyclotetradecane)
• Trigonal-Bipyramidal Geometry ina Cobalt(II) Complex with an Unsymmetrical Tripodal Ligand
• Oligonuclear Metal-Assembly of Antiferromagnetic Ni_4 and Ferromagnetic Ni_6 Clusters with Non-Schiff-Base Tetradentate Ligand
• cis-Dioxomolybdenu (VI) Complex with a Tripod-Like Tetradentate Ligand, N' , N' -Bis (2-hydroxy-3, 5-dimethylbenzyl)-N, N-dimethylethyl-enediamine
• A Tetranuclear Vanadium (III, III, IV, IV) Complex Formed by a Reaction of Bis(acetylacetonato)oxovanadium (IV) with a Thiolate Ligand
• Bismuth(III) Complexes of 2-Mercaptoethanol : Preparation, Structural and Spectroscopic Characterization, Antibactericidal Activity toward Helicobacter pylori, and Inhibitory Effect toward H. pylory-Produced Urease
• Synthesis and Characterization of Manganese(III) Complexes with 2-{N-[2-(4-Imidazolyl)ethyl]iminomethyl}phenol or 2-{N-[2-(2-Pyridyl)ethyl]iminomethyl}phenol
• Synthesis and Structural Characterization of Di-μPhenoxo-Bridged Dinuclear Iron(III) Complexes with Ferromagnetic or Weak Antiferromagnetic Coupling
• A Chain Compound Built Up by Alternated Arrangement of Molybdenum(II) Trifluoroacetate Dimer and 9,10-Anthraquinone
• Novel Tetranulear Cobalt(II)-Cobalt(III) Mixed-Valence Complexes with a Significant Difference in Magnetism
• Synthesis and Structural Characterization of a Unique Octanuclear Bismuth(III) Thiosalicylate Complex with a Disk-like Cluster Core
• Synthesis and Structural Characterization of Dinuclear Manganese(III) Complexes with Cyclam-Based Macrocyclic Ligands Having Schiff-Base Pendant Arms as Chelating Agents
• Synthesis and Structural Characterization of a Dinuclear Palladium(II) Complex with N,N',N'',N'''-Tetrakis(2-p-toluenesulfonamidoethyl)cyclam
• Monodentate, Didentate, and Tridentate Ligation of a Schiff-Base Ligand in a Tetranuclear Zinc(II) Complex
• Alkoxo-Bridged Dinuclear and Tetranuclear Copper(II) Complexes with Schiff-Bases Derived from Benzoylacetone and 1,n-Diamino-n'-hydroxyalkanes(n,n'= 3, 2 ; 4, 2 ; and 5, 3)
• Weak Antiferromagnetism in a μ-Alkoxo-μ-Pyrazolato-Bridged Dinnuclear Vanadium(IV) Complex
• Thiolato-Bridged Hexanuclear Cu^ICu^ Mixed-Valence Complex
• Syntheses, Crystal Structures, and Magnetic Properties of a Stable Aminoxyl Radical and Its Copper(II) Complex
• High Nuclearity in a Zinc (II) Complex with 1,3-Bis (salicylamino)-2-propanol
• Synthesis and Characterization of Tetranuclear Manganese (III) Complexes with 2,6-Bis(salicylideneaminomethyl)-4-methylphenol
• Ferromagnetically Coupled Dimanganese (III) Complex and Antiferromagnetically Coupled Diiron (III) Complex with Unsymmetrical Ligands
• Synthesis of a Tetranuclear Manganese Complex with a Cubane Core at the Mn^Mn^Mn^Mn^Oxidation Level
• Novel Thiolato-Bridged Tetranuclear Managenese (II) and Iron (II) Complexes with Adamantane-like Cores
• Synthesis and Characterization of Dinuclear and Tetranucler Mixed-Spin Nickel(II) Complexes with 2, 6-Bis(salidedaminomethyl)-4-methylphenol
• Novel Tetranuclear Nicke(II) Complex with a Mixed-Spin State Generated by Pairing of Dimers
• Cyclic Oligonuclear Fe_6Na_3 Complex with 2,6-Bis(salicylideneaminomethyl)-4-methylphenol
• Novel Pentanuclear Iron(III) Complex with 2,6-Bis(salicylideneaminomethyl)-4-methylphenol
• Synthesis and Structural Characterization of Manganese(II) Complexes with N, N'-Bis(2-pyridylmethylene)-1, 3-diaminopropan-2-ol or N, N'-Bis(2-pyridylmethylene)-1, 3-propanediamine
• Variable Coordination Geometries in Manganese(II) : Eight-, and Six-Coordinate Mn(II)Complexes with Pyridyl-Containing Schiff-Base Ligands
• Alkoxo-Bridged Trinuclear Manganese(III) Complex with an Isosceles Triangle Core
• Crystal and molecular structure of a binuclear copper(II) complex with 1,2,3,4-tetrakis(salicylideneamino)-2,3-dimethylbutane.
• X-ray crystal structure and electrochemical property of a novel monohydroxo-bridged binuclear cobalt(II) complex with N,N',N",N'"-tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane.
• Binuclear metal complexes. XXXI. Synthesis and magnetic property of binuclear manganese (III) complexes with 3-salicylideneamino-1-propanol and its homologues.
• Binuclear metal complexes. XXIII. Molecular structure of a hetero-metal binuclear complex, CuCo(fsaen) 3H2O(C18H18N2O9CoCu).
• Synthesis, spectral and magnetic properties and crystal structures of alkoxo-oxygen coordinated copper(II) complexes of N,N'-disubstituted malonamide and oxamide derivatives.
• The crystal structure and magnetic property of di-.MU.-propionato-O,O'-bis[N-p-tolylsalicylideneaminatocopper(II)].
• Binuclear metal complexes. XXXIX. Synthesis and properties of binuclear copper(II) complexes with (2-(2-pyridyl)ethylamino)-alkanols and (2-(2-pyridyl)ethylthio)alkanols.
• Crystal and molecular structure of a triply-thiolate-bridged binuclear cobalt(III) complex, (Co2{SCH(CH2CH2NH2)2}3)(ClO4)3H2O.
• Binuclear metal complexes. XLI. Crystal structure and unusual magnetic property of isothiocyanato{2-(2-(dimethylamino)ethylthio)ethanolato}copper(II).
• Syntheses and properties of copper(II) triperchlorates with N,N',N",N'"-tetrakis(2-aminoethyl)-1,4,8,11-tetraazacyclotetradecane and an anion.
• Binuclear metal complexes. XLIV. Crystal structures and magnetic properties of alkoxo-oxygen bridged binuclear copper(II) complexes with 2-(2-(dialkylamino)ethylthio)ethanol.
• Synthesis and characterization of imidazolate-bridged copper(II) complexes of triangular skeleton.
• Binuclear metal complexes XXXV. Synthesis and magnetism of binuclear copper(II) complexes with 3-(2-(dialkylamino)ethylthio)-1-propanols.
• Binuclear metal complexes. XXXVII. Crystal and molecular structure of a binuclear manganese(III) complex bridged by two alkoxo oxygens and two bidentate acetate ions.
• Structural, magnetic and IR spectroscopic characterization of dimeric copper(II) trichloroacetate adduct with benzonitrile. Nature of the copper(II)-bezonitrile bond.
• The crystal structures of a dicopper(II) complex containing two N4-macrocyclic rings connected with an ethylene chain.
• Synthesis and Crystal Structure of a Chain Complex of Molybdenum(II) Benzoate with 1,2-Bis(4-pyridyl)ethylene Having an N2-Adsorption Property
• Synthesis and Crystal Structure of a Chain Complex of Molybdenum(II) Benzoate and 1,2-Bis(4-pyridyl)ethane with an N2-Adsorption Property

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