Crystal and molecular structure of a triply-thiolate-bridged binuclear cobalt(III) complex, (Co2{SCH(CH2CH2NH2)2}3)(ClO4)3H2O.

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概要

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• The crystal structure of tris[μ-(1,5-diamino-3-pentanethiolato)-<I>N</I>,<I>N</I>′, μ-<I>S</I>]-dicobalt(III) perchlorate monohydrate was determined by the single-crystal X-ray diffraction method. The binuclear complex has a novel type of binuclear structure in which the two cobalt atoms are bridged by three thiolate sulfur atoms forming a face-shared bioctahedron.

• 公益社団法人 日本化学会の論文

著者

• Mikuriya Masahiro

  Department Of Chemistry And Open Research Center For Coordination Molecule-based Devices School Of S

• Kida Sigeo

  Department of Chemistry Wakayama University

• Murase Ichiro

  Laboratory of Chemistry, College of General Education, Kyushu University 01

• Kida Sigeo

  Department of Chemistry, Faculty of Science, Kyushu University 33

• Ueno Shigehiro

  Department of Chemistry, Faculty of Science, Kyushu University

• Murase Ichiro

  Laboratory of Chemistry, College of General Education, Kyushu University

• Ueno Shigehiro

  Department of Chemistry, Faculty of Science, Kyushu University 33

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