The crystal structure and magnetic property of di-.MU.-propionato-O,O'-bis[N-p-tolylsalicylideneaminatocopper(II)].
スポンサーリンク
概要
- 論文の詳細を見る
The crystal structure of di-μ-propionato-<I>O</I>,<I>O</I>′-bis[<I>N</I>-<I>p</I>-tolylsalicylideneaminatocopper(II)] was determined by X-ray diffraction method using the data collected by counter diffractometer techniques. The space group is P\bar1 and the cell constants are <I>a</I>=12.565(2), <I>b</I>=13.040(2), <I>c</I>=12.230(2) Å, α=107.73(1), β=115.72(1), γ=100.18(1)°, and <I>Z</I>=2. The structure was solved by the heavy atom method and refined by the block-diagonal leastsquares method to an <I>R</I> factor of 0.029. The crystal is composed of one-dimensional chains extended along the c axis, where the two copper atoms coordinated by the Schiff bases are bridged by two propionate groups. The magnetic property was discussed on the basis of the crystal structure.
- 公益社団法人 日本化学会の論文
著者
-
Tokii Tadashi
Department Of Chemistry And Applied Chemistry Facukty Of Science And Engineering Saga University
-
Muto Yoneichiro
Department Of Chemistry Faculty Of Science And Engineering Saga University
-
Mikuriya Masahiro
Department Of Chemistry And Open Research Center For Coordination Molecule-based Devices School Of S
-
Kida Sigeo
Department of Chemistry Wakayama University
-
Ueda Ikuhiko
College of General Education, Kyushu University 01
-
Ueda Ikuhiko
Colledge of General Education, Kyushu University 01
関連論文
- Characterization of Dimeric Copper(II) Trichloroacetate Complexes by Electron Spin Resonance, Infrared, and Electronic Reflectance Spectra. Correlation of Spectral Parameters with Molecular Geometry
- Polymer Complexes of Rhodium(II) Trifluoroacetamidate with Pyrazine, 4,4'-Bipyridine, and 1,4-Diazabicy-clo[2.2.2]octane
- Dinuclear Copper(II) Complexes of Free Radical Carboxylic Acids
- Antiferromagnetic Adducts of Copper(II) Propionate with Pyridyl Nitronyl Nitroxides
- Adduct Polymers and Dimers of Rhodium(II) Pivalate with Pyrazine, 4, 4'-Bipyridine, 1, 4-Diazabicyclo[2. 2. 2]octane, Triethylamine, and Pyridine
- Synthesis, X-Ray Structures, and Magnetic Properties of [Cu_2(piv)_4(Et_3N)_2] and [Cu_6(piv)_6(EtO)_6] (Hpiv = Pivalic Acid ) : Role of Base for Dinuclear Adduct and Oligonuclear Formation
- Self-assembly of Mixed-valent Ruthenium(II, III) Pivalate and Octacyanotungstate(V) Building Blocks
- Preparation and Electrochemical Properties of the Green Ytterbium (III) and Lutetium (III) Sandwich Complexes of Octabutoxy-Substituted Phthalocyanine
- A Polymer Complex [Cu(O_2CC_6F_5)_2-(pyz)]_n Formed from Copper(II) Pentafluorobenzoate and Pyrazine
- Synthesis and Characterization of Polynuclear Chain and Tetranuclear Complexes of Mixed-Valent Ruthenium(II, III) Pivalate with N, N'-Didentate Ligands
- Polymer and "Trimer-of-Dimers" Complexes Derived from [Rh_2(form)_4] (form^-=N, N'-Di-p-tolylformamidinate anion) and 1, 4-Diisocyanobenzene
- Syntheses and Magnetic Properties of Ruthenium(II, III) Pivalate Dimers Axially Coordinated by Nitronyl Nitroxide Radicals [Ru_2(O_2CCMe_3)_4-(L)_2]BF_4 and [{Ru_2(O_2CCMe_3)_4(L)_2}{Ru_2(O_2CCMe_3)_4(H_2O)_2}]_n(BF_4)_, L=2, 4, 4, 5, 5-Pentamethyl-4,
- Molecular-assembled Complexes of Mixed-valent Ruthenium Dimer with Hexacyanoferrate(III) and Hexacyanocobaltate(III) Ions
- Structure and Magnetic Properth of Ru(II,III) Dimer Axially Coordinated by the Niroxide Radical and Water [Ru_2(O_2CCMe_3)_4(nitph)(H_2O)]BF_4,nitph = 2-Phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl 3-N-oxide
- Structure and Magnetic Property of a Macrocyclic Tetranuclear Copper(II) Complex with Phenoxo- and Hydroxo-Bridges and Large and Small Cu-O-Cu Angles
- Structures and Magnetic Properties of Ruthenium(II, III) Pivalate Cation Dimers Axially Coordinated by Pyridyl Nitronyl Nitroxide Radicals through Their Pyridyl Nitrogen Atoms
- Synthesis and Structural Characterization of Thiolato-Bridged Zinc(II) Complexes with NNS-Tridentate Thiolic Ligands
- New Pyridine-modified Macrocycle and Its Ability to Encapsulate Four Divalent Metal Ions [Nickel(II), Manganese(II), and Zinc(II)] into the Ring
- Characterization of Dimeric (Carboxylato)copper(II) Complexes by Electron Spin Resonance Spectra. Correlation of ESR Parameters with Singlet-Triplet Energy Separations
- Structural and Magnetic Studies of Dimeric Copper(II) 2,2-Diphenylpropanoato and Triphenylacetato Complexes with Oxygen-Donor Ligands. The Cage Geometry of Dimeric α-Phenyl Substituted Copper(II) Carboxylates^
- Important Role of Tetrahydrofuran Ring in Activation of Hydrogen Peroxide in the Presence of Binuclear Iron(III) Complexes with Linear μ-Oxo Bridge
- Synthesis and Structure of Novel Hexanuclear Iron(III) Complexes with μ-Hydroxo-bis(μ-amino acid-O, O')diiron Cores
- A New "Dimer-of-Dimers" Complex Derived from Axial Coordination of 7, 7, 8, 8-Tetracyanoquinodimethane to Ru(II, III)Cation Dimer
- Chain Compound of Mixed - Valent Ruthenium Dimers Linked by Hydrogen - Bonding between the Axially Coordinated Nitronyl Nitroxide and Water Molecules
- Microporous Structure of a Chain Compound of Copper(II) Benzoate Bridged by Pyrazine
- Chain Compounds of Molybdenum(II) Trifluoroacetate Linked by p-Quinones [Mo_2(O_2CCF_3)_4(p-quin)]_n, p-quin = 9,10-anthraquinone, 2,6-dimethyl-1,4-benzoquinone, and 1,4-naphthoquinone
- Ferromagnetic Chain Complex of Ruthenium (II, III) Pivalate with Pyridy Nitronyl Nitroxide
- Structure and Magnetic Properties of a Chain Complex with Alternating Ru(II,III) Dimer and Nitroxide Radical Arrangement [Ru_2(O_2CCMe_3)_4(nitph)]_n(BF_4)_n, nitph = 2-Phenyl-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-N-Oxide
- Synthesis and Characterization of Thiolato-Bridged Trinuclear Heterometal Complexes with 2-[(3-Aminopropyl)amino]ethanethiol
- Chain Compounds of Rhodium(II) Trifluoroacetate Linked by p-Quinone Rh_2(O_2CCF_3)_4(p-Q)]_n, p-Q=1, 4-Benzoquinone, 1, 4-Naphthoquinone, and 2, 3-Dimethy1-1, 4-benzoquinone
- A Chain Complex of Ruthenium (II, III) Cation Dimer Linked by a Nitroxide Radical, [Ru_2 (O_2CCMe_3) _4 (NITPh)] _n (BF_4) _n (NITPh=2-Phenyl-4, 4, 5, 5-tetramethyl-4, 5-dihydro-1H-imidazolyl-1-oxy-3-oxide)
- Chain and Discrete Dimer Complexes of Molybdenum(II) Trifluoroacetate Axially Coordinated by p-Quinones, [Mo_2(O_2CCF_3)_4(2,6-Me-BQ]_n(2,6-Me-BQ=2,6-dimethyl-p-benzoquinone)and [Mo_2(O_2CCF_3)_4(2,6-t-Bu-BQ)_2 (2,6-t-Bu-BQ=2,6-di-t-butyl-p-benzoquinone)
- Linear Chain Compounds of Molybdenum(II) Acetate Linked by Phyrazine, 4,4'-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane
- Chain Compounds Formed by the Reaction of Copper(II) Carboxylate [Cu_2(O_2CR)_4] (R = C(CH_3)_3CCl_3 and Bridging Ligand L (L = Pyrazine, 4,4'-Bipyridine, and 1,4-Diazabicyclo[2.2.2]octane)
- Structure and Magnetic Properties of a Nitroxide Diruthenium(II,III) Complex, [Ru_2(O_2CCMe_3)_4(tempo)_2] {Ru_2(O_2CCMe_3)_4(H_2O)_2](BF_4)_2(tempo=2,2,6,6,-Tetramethylpiperidine-1-oxyl)
- Syntheses and Structural Characterization of Dinuclear and Trinuclear Iron(II) Complexes of Tridentate Thiolic Ligands with an NNS Donor Set
- Structure and Properties of a Compound Formed by the Reaction of Molybdenum(II) Trifluoroacetate with 4,4'-Bipyridine
- A Novel Chain Compound Composed of Rhodium(II) Pivalate Dimer and 1,4-Benzoquinone
- Novel Dinuclear Copper(II) Complexes with syn-syn and syn-anti Coordination Modes of Bis(μ-phosphinato)-bridges : Structures and Magnetic Properties
- Structural Characterization and Magnetic Properties of Triply Carboxylato-Bridged Dinuclear Copper(II) Complexes
- Assembly of a Tetranuclear Mixed - Valence Manganese(II, III) Complex from a Binuclear Manganese(II) Complex by Photo - Irradiation
- Synthesis and Crystal Structure of a Novel Hexanuclear Zr(IV) Complex with Hydroxo and Carboxylato Bridging
- The First Example of μ-Oxo-bis(μ-carboxylato)dioxovanadium(IV, V)Complex
- Synthesis, Structure, and Magnetic Properties of Dinuclear Copper(II) Complexes with Novel Triple Carboxylato-Bridging Linkages
- Magnetic Properties and Crystal Structures of Binuclear Copper(II) Complexes with Heterocyclic Thione Donors of 1,3-Bis(gydroxymethyl)-2-imidazolidinethione and 1-Hydroxymethyl-3-methyl-2-imidazolidinethione
- Synthesis, Structure, and Magnetic Properties of Triply Carboxylato-Bridged Dimanganese(II) Complexes
- Synthesis and Structural Characterization of Thiolato-Bridged Tetranuclear Palladium(II) Complexes with N,N,S-Tridentate Ligands
- Synthesis and Structural Characterization of Tetranuclear Zinc(II) Complexes with a Linear Array
- One-Dimensional Coordination Polymers from the Self-Assembly of Copper(II) Carboxylates and 4, 4'-Dithiobis(pyridine)
- Synthesis, Crystal Structures, and Magnetic Properties of Dinuclear and Hexanuclear Copper(II) Complexes with Cyclam-Based Macrocyclic Ligands Having Four Schiff-Base Pendant Arms
- Synthesis and Structure of Tetrakis Carboxylato-Bridged Dinuclear Manganese(II)Quinoline Complexes, with Carboxylates Diphenylacetate and 2, 2-Diphenylpropanoate
- Isolation of a Unique Hexanuclear [Bi_6O_4OH(cit)_3(H_2O)_3]^ Cluster from the Bismuth-Containing Ulcer Healing Agent "Colloidal Bismuth Subcitrate (CBS)"
- Dinuclear Manganese(III) Complex with Cyclam-based Dodecadentate Ligand Bearing Schiff-base Pendants (Cyclam = 1, 4, 8, 11-Tetraazacyclotetradecane)
- Synthesis, Structure, and Magnetic Properties of a Novel Copper(II) Analogue of the Hemerythrin Active Center
- Trigonal-Bipyramidal Geometry ina Cobalt(II) Complex with an Unsymmetrical Tripodal Ligand
- Oligonuclear Metal-Assembly of Antiferromagnetic Ni_4 and Ferromagnetic Ni_6 Clusters with Non-Schiff-Base Tetradentate Ligand
- cis-Dioxomolybdenu (VI) Complex with a Tripod-Like Tetradentate Ligand, N' , N' -Bis (2-hydroxy-3, 5-dimethylbenzyl)-N, N-dimethylethyl-enediamine
- A Tetranuclear Vanadium (III, III, IV, IV) Complex Formed by a Reaction of Bis(acetylacetonato)oxovanadium (IV) with a Thiolate Ligand
- Bismuth(III) Complexes of 2-Mercaptoethanol : Preparation, Structural and Spectroscopic Characterization, Antibactericidal Activity toward Helicobacter pylori, and Inhibitory Effect toward H. pylory-Produced Urease
- Synthesis and Characterization of Manganese(III) Complexes with 2-{N-[2-(4-Imidazolyl)ethyl]iminomethyl}phenol or 2-{N-[2-(2-Pyridyl)ethyl]iminomethyl}phenol
- Synthesis and Structural Characterization of Di-μPhenoxo-Bridged Dinuclear Iron(III) Complexes with Ferromagnetic or Weak Antiferromagnetic Coupling
- Iron Chelates in Biological Systems. Its Relevance to Induction of Pathogenesis of Tissue Damage and Carcinogenesis
- A Chain Compound Built Up by Alternated Arrangement of Molybdenum(II) Trifluoroacetate Dimer and 9,10-Anthraquinone
- Novel Tetranulear Cobalt(II)-Cobalt(III) Mixed-Valence Complexes with a Significant Difference in Magnetism
- Synthesis and Structural Characterization of a Unique Octanuclear Bismuth(III) Thiosalicylate Complex with a Disk-like Cluster Core
- Synthesis and Structural Characterization of Dinuclear Manganese(III) Complexes with Cyclam-Based Macrocyclic Ligands Having Schiff-Base Pendant Arms as Chelating Agents
- Synthesis and Structural Characterization of a Dinuclear Palladium(II) Complex with N,N',N'',N'''-Tetrakis(2-p-toluenesulfonamidoethyl)cyclam
- Monodentate, Didentate, and Tridentate Ligation of a Schiff-Base Ligand in a Tetranuclear Zinc(II) Complex
- Alkoxo-Bridged Dinuclear and Tetranuclear Copper(II) Complexes with Schiff-Bases Derived from Benzoylacetone and 1,n-Diamino-n'-hydroxyalkanes(n,n'= 3, 2 ; 4, 2 ; and 5, 3)
- Weak Antiferromagnetism in a μ-Alkoxo-μ-Pyrazolato-Bridged Dinnuclear Vanadium(IV) Complex
- Thiolato-Bridged Hexanuclear Cu^ICu^ Mixed-Valence Complex
- Synthesis and Characterization of Tetranuclear Manganese (III) Complexes with 2,6-Bis(salicylideneaminomethyl)-4-methylphenol
- Ferromagnetically Coupled Dimanganese (III) Complex and Antiferromagnetically Coupled Diiron (III) Complex with Unsymmetrical Ligands
- Structural, Magnetic, and Spectroscopic Characterization of the Pyridine Complexes of Copper(II) Triphenylacetate: A Dimeric Copper(II) Triphenylacetate-Pyridine Complex with Distorted Trigonal Bipyramidal Geometry Around Copper.
- Magnetic properties of dimeric copper(II) 2,2-dimethylpropanoate complexes.
- Structural, magnetic and spectroscopic characterization of novel di-.MU.-carboxylato-bridged binuclear copper(II) complexes with 1,10-phenanthroline.
- The magnetic properties of the ammonium chloride adducts of copper(II) fluoroacetate and copper(II) bromoacetate.
- The magnetic properties of the copper(II) (disubstituted acetate) adducts with ammonium chloride.
- Magnetic properties of dimeric copper(II) trichloroacetate adducts with 3-substituted pyridines.
- Two Modifications of Bi-Nuclear Copper(II) Chloride Complexes with N-Methylsalicylideneimine
- The magnetic properties of the copper(II) complexes with .OMEGA.-amino carboxylic acids.
- The magnetic properties of Cu(CH3COO)22NH4Cl and NH4Cu(HCOO)Cl2.
- Synthesis and magnetic susceptibility of dimeric copper(II) acetate adducts with triphenylphosphine or triphenylphosphine oxide.
- The magnetic properties of the copper(II) alkanoate adducts with benzimidazole and related nitrogen donors.
- The magnetic properties of copper(II) alkanoate adducts with pyridine and quinoline analogues.
- The magnetic properties of the copper(II) alkanoate adducts with cyclic ethers and tertiary amines.
- Dimeric copper(II) nitrato and chloro complexes with N-(3-dimethyl-aminopropyl)salicylideneaminato ligand protonated at the terminal nitrogen.
- Magnetic and spectral properties of dimeric copper(II) phenylpropynoate complexes.
- Magnetic and spectral properties of binuclear nickel(II) nitrato and acetato complexes of tridentate schiff bases derived from salicylaldehydes and N-substituted trimethylenediamines.
- The crystal structure and magnetic property of di-.MU.-propionato-O,O'-bis[N-p-tolylsalicylideneaminatocopper(II)].
- The magnetic properties of the ammonium chloride adducts of copper(II) chloroacetates.
- The Magnetic Susceptibility of Two Coupled Dimers Consisting of S=1/2 Spins
- Syntheses and magnetic properties of three modifications of dichloro[2-(hydroxymethyl)pyridine N-oxide]copper II.
- Factors Affecting: the Line-width of Nitrogen Superhyperfine Structure in the ESR Spectra of Copper(II) Complexes
- Binuclear Structure of Copper(II) 2-Pyridinolate Complex
- Magnetic properties of copper(II) complexes of phenylboronic acid.
- Spectral and Magnetic Studies on Bi- and Tri-Nuclear Complexes Derived from Copper(II) Complexes with Tetradentate Schiff Base and One of the Chlorides, Nitrates and Perchlorates of Copper(II), Nickel(II), Cobalt(II) and Zinc(II)
- Binuclear Metal Complexes. VII. Preparation and Properties of Binuclear Copper(II) and Nickel(II) Complexes of Hydrogen-bridged Macrocycles
- The 2:1 adduct of chloro[N-(2-dimethylaminoethyl)salicylideneaminato]copper(II) with chlorides of copper(II), manganese(II), and nickel(II).
- Structural, magnetic and IR spectroscopic characterization of dimeric copper(II) trichloroacetate adduct with benzonitrile. Nature of the copper(II)-bezonitrile bond.