Magnetic and spectral properties of dimeric copper(II) phenylpropynoate complexes.
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概要
- 論文の詳細を見る
Dimeric copper(II) phenylpropynoate adducts [Cu(Ph–C≡C–COO)<SUB>2</SUB>·L]<SUB>2</SUB>, where L=benzonitrile, 3,5-dichloropyridine, dimethyl sulfoxide and triphenylphosphine oxide, have been synthesized in order to study the influence of the C≡C group linked to the COO group upon the extent of antiferromagnetic interaction between the two metal ions. Magnetic susceptibility measurements between 80 and 300 K show that the singlet-triplet separation (−2<I>J</I>) ranges from 283 to 318 cm<SUP>−1</SUP>. The magnetic behavior of the non-adduct compound Cu(Ph–C≡C–COO)<SUB>2</SUB> is interpreted by taking an inter-dimer interaction into consideration.
- 公益社団法人 日本化学会の論文
著者
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Tokii Tadashi
Department Of Chemistry And Applied Chemistry Facukty Of Science And Engineering Saga University
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Sasaki Ayako
Department Of Biofunctional Science Faculty Of Agriculture And Life Science Hirosaki University
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Nakashima Michio
Department Of Chemistry Faculty Of Science And Engineering Saga University
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Muto Yoneichiro
Department Of Chemistry Faculty Of Science And Engineering Saga University
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Sasaki Ayako
Department of Chemistry, Faculty of Science and Engineering, Saga University
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