The magnetic properties of Cu(CH3COO)22NH4Cl and NH4Cu(HCOO)Cl2.
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概要
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The temperature dependence of the magnetic susceptibility of Cu(CH<SUB>3</SUB>COO)<SUB>2</SUB>·2NH<SUB>4</SUB>Cl obeys the Bleaney-Bowers equation, indicating the existence of the anionic copper(II) acetate dinuclear unit. The exchange integral, <I>J</I>/<I>k</I>, is equal to −205 K. For NH<SUB>4</SUB>Cu(HCOO)Cl<SUB>2</SUB>, the structure containing copper(II) formate layers connected by tetrachlorocuprate(II) bridges is presumed on the basis of the value of the Weiss constant.
- 公益社団法人 日本化学会の論文
著者
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Muto Yoneichiro
Department Of Chemistry Faculty Of Science And Engineering Saga University
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Emori Shuji
Department Of Chemistry And Applied Chemistry Faculty Of Science And Engineering Saga University
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