Preparation and magnetic properties of the copper(II) mixed carboxylates with haloacetate and ammonioacetate.

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概要

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• Copper(II) mixed carboxylate compounds, CuX(X′CH<SUB>2</SUB>COO)(R<SUB>3</SUB>NCH<SUB>2</SUB>COO)·<I>m</I>H<SUB>2</SUB>O (X=C1, Br; X′=F, Cl; R=, CH<SUB>3</SUB>), were prepared, and then characterized by means of magnetic susceptibility and IR-spectroscopy. The mixed carboxylates with betaine have the copper(II) acetate-type dinuclear structures. The amount of spin-exchange coupling through betaine bridges was estimated.

• 公益社団法人 日本化学会の論文

著者

• Emori Shuji

  Department Of Chemistry And Applied Chemistry Faculty Of Science And Engineering Saga University

• Yoshidzu Kayoko

  Department of Chemistry, Faculty of Science and Engineering, Saga University

関連論文

• Magneto-Structural Correlations in Alkoxo-Bridged Copper(II) Compounds
• Magneto-Structural Correlations in Phenoxo-Bridged Metal(II) Compounds. Magnetic Properties of (R_4N)_2 [Co_2 Cl_4(4-XC_6H_4O)_2](X=H, CH_3 ; R=CH_3, C_2H_5)
• Magnetic Studies on the Dissociation Equilibria of Dinuclear Nickel(II) Alkanoates in Non-Aqueous Solutions
• Magneto-Structural Correlations in Phenoxo-Bridged Copper(II) Compounds
• The magnetic properties of copper(II) 3- and 4-substituted benzoate adducts with quinoline and 4-methylquinoline.
• The magnetic properties of the ammonium chloride adducts of copper(II) fluoroacetate and copper(II) bromoacetate.
• The magnetic properties of the copper(II) (disubstituted acetate) adducts with ammonium chloride.
• The magnetic properties of the copper(II) complexes with .OMEGA.-amino carboxylic acids.
• The magnetic properties of Cu(CH3COO)22NH4Cl and NH4Cu(HCOO)Cl2.
• The magnetic properties of the copper(II) alkanoate adducts with benzimidazole and related nitrogen donors.
• The magnetic properties of copper(II) alkanoate adducts with pyridine and quinoline analogues.
• The magnetic properties of the copper(II) alkanoate adducts with cyclic ethers and tertiary amines.
• Magnetic and spectral properties of binuclear nickel(II) nitrato and acetato complexes of tridentate schiff bases derived from salicylaldehydes and N-substituted trimethylenediamines.
• Preparation and magnetic properties of the copper(II) mixed carboxylates with haloacetate and ammonioacetate.
• The magnetic properties of the ammonium chloride adducts of copper(II) chloroacetates.
• The magnetic properties of dinuclear copper(II) 2-fluoroalkanoates.
• The Magnetic Susceptibility of Two Coupled Dimers Consisting of S=1/2 Spins
• The magnetic properties of copper(II) 3- and 5-substituted 2-pyridinolates.
• The Magnetic Properties of the 2-Pyridone Adducts of Copper(II) Benzoates and Related Copper(II) Compounds.
• Binuclear Structure of Copper(II) 2-Pyridinolate Complex
• Magnetic properties of copper(II) complexes of phenylboronic acid.

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