Synthesis and magnetic susceptibility of dimeric copper(II) acetate adducts with triphenylphosphine or triphenylphosphine oxide.

スポンサーリンク

概要

• 論文の詳細を見る

• Two compounds of stoichiometry Cu(CH<SUB>3</SUB>COO)<SUB>2</SUB>·L (L=triphenylphosphine or triphenylphosphine oxide) were prepared. These compounds display the antiferromagnetic behavior typical of dimeric copper(II) carboxylates. The singlet-triplet splitting energy is 371 cm<SUP>−1</SUP> for the phosphine adduct and 319 cm<SUP>−1</SUP> for the phosphine oxide adduct.

• 公益社団法人 日本化学会の論文

著者

• Tokii Tadashi

  Department Of Chemistry And Applied Chemistry Facukty Of Science And Engineering Saga University

• MUTO Yoneichiro

  Department of Chemistry, Faculty of Science and Engineering, Saga University

• Muto Yoneichiro

  Department Of Chemistry Faculty Of Science And Engineering Saga University

• Ikeda Toyoaki

  Department of Chemistry, Faculty of Science and Engineering, Saga University

関連論文

• Characterization of Dimeric Copper(II) Trichloroacetate Complexes by Electron Spin Resonance, Infrared, and Electronic Reflectance Spectra. Correlation of Spectral Parameters with Molecular Geometry
• Preparation and Electrochemical Properties of the Green Ytterbium (III) and Lutetium (III) Sandwich Complexes of Octabutoxy-Substituted Phthalocyanine
• Characterization of Dimeric (Carboxylato)copper(II) Complexes by Electron Spin Resonance Spectra. Correlation of ESR Parameters with Singlet-Triplet Energy Separations
• Structural and Magnetic Studies of Dimeric Copper(II) 2,2-Diphenylpropanoato and Triphenylacetato Complexes with Oxygen-Donor Ligands. The Cage Geometry of Dimeric α-Phenyl Substituted Copper(II) Carboxylates^
• Important Role of Tetrahydrofuran Ring in Activation of Hydrogen Peroxide in the Presence of Binuclear Iron(III) Complexes with Linear μ-Oxo Bridge
• Synthesis and Structure of Novel Hexanuclear Iron(III) Complexes with μ-Hydroxo-bis(μ-amino acid-O, O')diiron Cores
• Novel Dinuclear Copper(II) Complexes with syn-syn and syn-anti Coordination Modes of Bis(μ-phosphinato)-bridges : Structures and Magnetic Properties
• Structural Characterization and Magnetic Properties of Triply Carboxylato-Bridged Dinuclear Copper(II) Complexes
• Assembly of a Tetranuclear Mixed - Valence Manganese(II, III) Complex from a Binuclear Manganese(II) Complex by Photo - Irradiation
• Synthesis and Crystal Structure of a Novel Hexanuclear Zr(IV) Complex with Hydroxo and Carboxylato Bridging
• The First Example of μ-Oxo-bis(μ-carboxylato)dioxovanadium(IV, V)Complex
• Synthesis, Structure, and Magnetic Properties of Dinuclear Copper(II) Complexes with Novel Triple Carboxylato-Bridging Linkages
• Magnetic Properties and Crystal Structures of Binuclear Copper(II) Complexes with Heterocyclic Thione Donors of 1,3-Bis(gydroxymethyl)-2-imidazolidinethione and 1-Hydroxymethyl-3-methyl-2-imidazolidinethione
• Synthesis, Structure, and Magnetic Properties of Triply Carboxylato-Bridged Dimanganese(II) Complexes
• Synthesis and Structure of Tetrakis Carboxylato-Bridged Dinuclear Manganese(II)Quinoline Complexes, with Carboxylates Diphenylacetate and 2, 2-Diphenylpropanoate
• Synthesis, Structure, and Magnetic Properties of a Novel Copper(II) Analogue of the Hemerythrin Active Center
• Synthesis and Structural Characterization of Di-μPhenoxo-Bridged Dinuclear Iron(III) Complexes with Ferromagnetic or Weak Antiferromagnetic Coupling
• Iron Chelates in Biological Systems. Its Relevance to Induction of Pathogenesis of Tissue Damage and Carcinogenesis
• Synthesis and Characterization of Tetranuclear Manganese (III) Complexes with 2,6-Bis(salicylideneaminomethyl)-4-methylphenol
• Ferromagnetically Coupled Dimanganese (III) Complex and Antiferromagnetically Coupled Diiron (III) Complex with Unsymmetrical Ligands
• Structural, Magnetic, and Spectroscopic Characterization of the Pyridine Complexes of Copper(II) Triphenylacetate: A Dimeric Copper(II) Triphenylacetate-Pyridine Complex with Distorted Trigonal Bipyramidal Geometry Around Copper.
• Magnetic properties of dimeric copper(II) 2,2-dimethylpropanoate complexes.
• Structural, magnetic and spectroscopic characterization of novel di-.MU.-carboxylato-bridged binuclear copper(II) complexes with 1,10-phenanthroline.
• The magnetic properties of the ammonium chloride adducts of copper(II) fluoroacetate and copper(II) bromoacetate.
• The magnetic properties of the copper(II) (disubstituted acetate) adducts with ammonium chloride.
• Magnetic properties of dimeric copper(II) trichloroacetate adducts with 3-substituted pyridines.
• Two Modifications of Bi-Nuclear Copper(II) Chloride Complexes with N-Methylsalicylideneimine
• The magnetic properties of the copper(II) complexes with .OMEGA.-amino carboxylic acids.
• The magnetic properties of Cu(CH3COO)22NH4Cl and NH4Cu(HCOO)Cl2.
• Synthesis and magnetic susceptibility of dimeric copper(II) acetate adducts with triphenylphosphine or triphenylphosphine oxide.
• The magnetic properties of the copper(II) alkanoate adducts with benzimidazole and related nitrogen donors.
• The magnetic properties of copper(II) alkanoate adducts with pyridine and quinoline analogues.
• The magnetic properties of the copper(II) alkanoate adducts with cyclic ethers and tertiary amines.
• Dimeric copper(II) nitrato and chloro complexes with N-(3-dimethyl-aminopropyl)salicylideneaminato ligand protonated at the terminal nitrogen.
• Magnetic and spectral properties of dimeric copper(II) phenylpropynoate complexes.
• Magnetic and spectral properties of binuclear nickel(II) nitrato and acetato complexes of tridentate schiff bases derived from salicylaldehydes and N-substituted trimethylenediamines.
• The crystal structure and magnetic property of di-.MU.-propionato-O,O'-bis[N-p-tolylsalicylideneaminatocopper(II)].
• The magnetic properties of the ammonium chloride adducts of copper(II) chloroacetates.
• The Magnetic Susceptibility of Two Coupled Dimers Consisting of S=1/2 Spins
• Syntheses and magnetic properties of three modifications of dichloro[2-(hydroxymethyl)pyridine N-oxide]copper II.
• Factors Affecting: the Line-width of Nitrogen Superhyperfine Structure in the ESR Spectra of Copper(II) Complexes
• Binuclear Structure of Copper(II) 2-Pyridinolate Complex
• Magnetic properties of copper(II) complexes of phenylboronic acid.
• Spectral and Magnetic Studies on Bi- and Tri-Nuclear Complexes Derived from Copper(II) Complexes with Tetradentate Schiff Base and One of the Chlorides, Nitrates and Perchlorates of Copper(II), Nickel(II), Cobalt(II) and Zinc(II)
• Binuclear Metal Complexes. VII. Preparation and Properties of Binuclear Copper(II) and Nickel(II) Complexes of Hydrogen-bridged Macrocycles
• The 2:1 adduct of chloro[N-(2-dimethylaminoethyl)salicylideneaminato]copper(II) with chlorides of copper(II), manganese(II), and nickel(II).
• Structural, magnetic and IR spectroscopic characterization of dimeric copper(II) trichloroacetate adduct with benzonitrile. Nature of the copper(II)-bezonitrile bond.

もっと見る 閉じる

スポンサーリンク