A Study on Spontaneous Resolution of Cobalt(III) Complex Salts
スポンサーリンク
概要
- 論文の詳細を見る
Solubility of the racemic and optically active isomers of [Co(ox)en<SUB>2</SUB>]X, [CoCO<SUB>3</SUB>en<SUB>2</SUB>]X, <I>cis</I>-[Co(NO<SUB>2</SUB>)<SUB>2</SUB>en<SUB>2</SUB>]X and M[Co(edta)] in water was determined at 5–60 °C (X=Cl, Br, and I; M=NH<SUB>4</SUB> and K). The correlation between solubility of the spontaneously resolved racemic complex and of the corresponding optically active isomer is discussed. Spontaneous resolutions were observed for [Co(ox)en<SUB>2</SUB>]X (X=Cl, Cl·H<SUB>2</SUB>O, and Br·H<SUB>2</SUB>O), <I>cis</I>-[Co(NO<SUB>2</SUB>)<SUB>2</SUB>-en<SUB>2</SUB>]X (X=Cl and Br) and M[Co(edta)]·2H<SUB>2</SUB>O (M=NH<SUB>4</SUB> and K).
- 公益社団法人 日本化学会の論文
著者
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Yamanari Kazuaki
Department Of Chemisry Faculty Of Science Osaka University
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Shimura Yoichi
Department of Chemistry Faculty of Science Osaka University
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Hidaka Jinsai
Department of Chemistry Faculty of Science Osaka University
関連論文
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- タイトル無し
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