Preparation and characterization of cobalt(III) complexes with S,S-bridge R,S-sexidentate-N2,S2,O2 type ligands. Crystal structure of (+)5C6D0-((2R,9S)-diamino-3,3,8,8-tetramethyl-4,7-dithia-1,10-decanedioato)cobalt(III) ion.

スポンサーリンク

概要

• 論文の詳細を見る

• [Co(<I>R</I>,<I>S</I>-sexidentate-<I>N</I><SUB>2</SUB>,<I>S</I><SUB>2</SUB>,<I>O</I><SUB>2</SUB>)] and [Co(<I>R</I>-terdentate-<I>N</I>,<I>S</I>,<I>O</I>)(<I>S</I>-<I>terdentate</I>-<I>N</I>,<I>S</I>,<I>O</I>)] type complexes, including the title complex cation, [Co(<I>R</I>,<I>S</I>-ebp)]<SUP>+</SUP>, were prepared and resolved. The crystal structure and absolute configuration of the (+)<SUB>560</SUB><SUP>CD</SUP>-[Co(<I>R</I>,<I>S</I>-ebp)]<SUP>+</SUP> isomer were determined by X-ray diffraction. The complex cation has an [<I>S</I>] configuration. The <I>R</I>,<I>S</I>-ebp coordinates as a sexidentate, of which two sulfur donor atoms take selectively <I>R</I>(<I>S</I>). The absorption and CD spectra are discussed in comparison with those of the related complexes.

著者

• Okamoto Ken-ichi

  Department Of Advanced Materials Science & Engineering Faculty Of Engineering Yamaguchi Universi

• Hidaka Jinsai

  Department of Chemistry Faculty of Science Osaka University

• Nomoto Masayo

  Department of Chemistry, University of Tsukuba

• Kanesaka Mikako

  Department of Chemistry, University of Tsukuba

関連論文

• Five-Coordinate Geometry of Cadmium(II) with Octahedral Bidentate-S,S Complex-Ligand cis(s)-[Co(aet)_2(en)]^+(aet=2-aminoethanethiolate) : Synthesis, Crystal Structures and Interconversion of S-Bridged Co^Cd^ Polynuclear Complexes
• Preparation and Properties of S-Bridged Co^III Ag^I_3Co^III Pentanuclear Complexes Having a Triple Helical Chirality. Crystal Structure of [Ag_3{Co(aet)_3}_2](BF_4)_3 (aet = 2-Aminoethanethiolate)
• Optically Active S-Bridged Co^Pd^ Polynuclear Complexes Derived from ΔΔ-[Ni{Co(aet)_2(R-pn)}_2]^ (aet=2-Aminoethanethiolate, R-pn=(R)-1,2-Propanediamine
• Synthesis, Crystal Structures, and Some Properties of S-Bridged Pt(II)-M(III) (M=Co, Rh) Dinuclear Complexes with Square-Planar and Octahedral Geometries
• Stereoselectivity for S-Bridged Polynuclear Transition Metal Complexes Formed by Aggregation of Octahedral Complexes to Square-Planar Palladium(II)
• Preparation, Characterization, and Some Properties of Novel Dinuclear Complexes with a Coordinated Bridging Disulfide Bond. Crystal Structures of Δ_RΛ_S-[M_2(2-aminoethanethiolato)_4(cystamine)]^ (M = Ir^, Rh^)
• Synthesis, Crystal Structures, and Properties of S-Bridged Pt(II)-Ni(II) Dinuclear Complexes : Conversion of Square-Planar [Ni(aet)_2] to Octahedral Geometry by Forming an S-Bridged Structure with Pt(II) (aet=2-Aminoethanethiolate)
• Preparation, Stereochemistry, and Reactivity of Linear-Type S-Bridged MCr^M (M=Rh^,Ir^) Trinuclear Complexes with 2-Aminoethanethiolate (aet). Crystal Structures of Δ∧-[Cr{M(aet)_3}_2]^
• Syntheses and Some Properties of S-Bridged Pentanuclear Co(III)-Hg(II) or Rh(III)-Hg(II) Complexes with 2-Aminoethanethiolate. Crystal Structures of [{Rh(aet)_3}_2(HgCl_2)_3] and [{Rh(aet)_3}_2Hg_3(NO_3)_4](NO_3)_2
• Transfer of 2-Aminoethanethiolate (aet) from Nickel(II) to Cobalt(III) Coordination Sphere. Synsesis, Crystal Structure, and Some Properties of an S-Bridged Ttinuclear Complex [Ni{Co(aet)_2(en)}_2]^
• Selective Formation of Alkoxo-bridged Titanium(IV) Polynuclear Complexes with Polyaminopolycarboxylate : First Titanium(IV) Octanuclear Complex Containing Cubic-type {Ti_4(μ-oxo)_4}_2(μ-alkoxo)_4 Core
• On the Development of Naphthalene-Based Sulfonated Polyimide Membranes for Fuel Cell Applications
• Preparation and Gas Permeation Properties of Composite Carbon Molecular Sieve Membranes Derived from Polyimides with Thermally Decomposable Sulfonic Acid Salt and/or Hexafluoroisopropylidene Group
• Synthesis and Gas Permeation Properties of Star-like Poly(ethylene oxide)s Using Hyperbranched Polyimide as Central Core
• Synthesis and Characterization of Polyimides with Pendant Phosphonate Ester Groups
• Carbon Molecular Sieve Membrane Prepared from Phenolic Resin
• Selective Permeation of Carbon Dioxide through Amine-modified Polyimide Membranes
• The Effects of CO_2-Conditioning of Polymers on Positron Annihilation and Gas Permeation Properties
• PERVAPORATION-AIDED ESTERIFICATION OF OLEIC ACID
• Selective Permeation of Carbon Dioxide over Nitrogen through Polyethyleneoxide-Containing Polyimide Membranes
• VAPOR-PERMEATION SEPARATION OF WATER-ETHANOL MIXTURES BY ASYMMETRIC POLYIMIDE HOLLOW-FIBER MEMBRANE MODULES
• Phylogenetic Position of Kinetoplastid Protozoa Inferred from the Protein Phylogenies of Elongation Factors 1α and 2^1
• A New Class of S-Bridged Pentanuclear Complexes with a Triple Helical Chirality. Crystal Structure of [{Rh^(aet)_3}_2(Hg^Cl_2)_3](aet=2-aminoethanethiolate)
• Stereoselective Formation and Characterization of S-Bridged Dinuclear Λ- and Δ-[Co{Co(didentate-N,S)_3}(_D-pen-N,O,S)]-Type Complexes (didentate=2-Aminoethanethiolate, _L-Cysteinate, and _D-Penicillaminate (_D-pen))
• Photochemistry of Cobalt(III) Complexes. II. Cobalt(III) Complex with a Co-C-S Three-Membered Ring Prepared by Photodecarboxylation of 2,2'-Thiodiacetato Complex. Crystal Structure of (-)^_-fac-trans(NH,O)-[Co(CH_2SCH_2COO)(dien)]ClO_4
• Complete Nucleotide Sequences of the Genes Encoding Translation Elongation Factors 1α and 2 from a microsporidian parasite, Glugea plecoglossi: Implications for the Deepest Branching of Eukaryotes
• Synthesis and Structure of Unprecedented Carboxylate-bridged Heteronuclear Cr(III)-Nb(III) Complex
• First Conversion of a Square-planar [Ni(aet)_2] to an Octahederal [Ni(aet)_2L] by Forming S-Bridged Structure with Pt(II) (aet=2-Aminoethanethiolate: L = (H_2O)_2 or 2,2'-Bipyridine)
• Novel Aggregation of fac(S)-[Rh(aet)_3]by Square-Planar Palladium(II) : Crystal Structure of Spontaneously Resolved Rh^_3Pd^_2 Pentanuclear Complex [Pd{Pd(aet)}{Rh(aet)_2}{Rh(aet)_3}_2]Br_4(aet=2-Aminoethanethiolate)
• Effects of Proteolytic Digestion on the Control Mechanism of Ciliary Orientation in Ciliated Sheets from Paramecium
• Mononuclear Copper(II) Hydroxo Comples: Structural Effect of a 3-Position of Tris(pyrazolyl)borates
• Synthesis, Structure and Reactivity of Phenoxo Copper(II) Complexes, Cu(OAr)(HB(3, 5-Pr^i_2pz)_3)(Ar=C_6H_4-4-F, 2, 6-Me_2C_6H_3, 6-Bu^t_2C_6H_3)
• Oxygen Atom Transfer Catalytic Property of Oxorhenium(V) Complex with 2-Methylquinolin-8-ylamide and Tetrachlorocatecholate
• Crystal Structure of Pyrazolato-bridged Copper (I) Polynuclear Complexes
• Selective Formation and Characterization of Oxorhenium(V) Complexes with 2-Methylquinolin-8-ylamido (Hamq). Interconversion between [ReOX_2(Hamq)(PPh_3)] and [ReOX_2(Hamq)(OPPh_3)] (X=Cl, Br)
• UV-Vis Absorption and CD Spectroelectrochemical Studies on S-Bridged Polycobalt(III) Complexes with 2-Aminoethanethiolate or L-Cysteinate
• Novel Alkoxo-Bridged Lanthanide(III) Dinuclear Complexes : Crystal Structure of Na_4[Yb_2(μ-dpta-O)_2](H_4dpta-OH = 1, 3-Diamino-2-hydroxypropane-N, N, N', N'-tetraacetic acid
• Optically Active S-Bridged Co^M(M=Pt^, Hg^, Au^I) Polynuclear Complexes Derived from ΔΔ-[Ni{Co(aet)_2(R-pn)}_2]^(aet=2-Aminoethanethiolate, R-pn=(R)-1,2-Propanediamine
• Crystal Structures and Spectroscopic Characterization of Linear-Type S-Bridged Trinuclear Complexes 〓〓-and 〓〓/〓〓-[Re^{Rh^(aet)_3}_2]^ (aet = 2-Aminoethanethiolate)
• Structural Effects on Nitratocopper(II) Complexes of Tris(pyrazolyl)borates
• Synthesis, Crystal Structure, and Some Spectrochemical Properties of S-Bridged Hexanuclear Zinc(II) Complex with 2-Aminoethanethiolate: Formation of Zn_3S_3-and Zn_4S_4-Cyclic Cores
• Structural Characteristics of S-Bridged Trinuclear Complexes[{Pd(terpy)}_2{Pd(aet)_2}]^(terpy=2,2' : 6',2"-Terpyridine, aet=2-Aminoethanethiolate): Effects of Counter Anions and Solvent on Intra- and Intermolecular Stacking Arrangements
• Syntheses, Crystal Structures, and Some Spectrochemical Properties of S-Bridged Tetranuclear Complexes with Stacking Arrangements Composed of Planar Palladium(II) Units
• Crystal Structure and Spectrochemical Properties of a Dinuclear Palladiun(II) Complex with 2,3,5,6-Tetra(2-pyridyl)-pyrazine
• Preparation and Structure of a Novel Tetranuclear Mixed-Valence Vanadium(IV/V)complexes Having Alkoxo and Groups
• Enantioselective Aggregation of Cobalt(III) Octahedrons in a One-Dimensional S-Bridged Co^Ag^I Array That Leads to Spontaneous Resolution
• Chiral-Selective Formation of S-Bridged Co^Pd^Co^ Trinuclear Complexes by Using trans(N)-[Co(D-pen-N,O,S)_2]^- as a Bidentate-S,S Complexed-Ligand (D-pen=D-Penicillaminate
• A Novel Dinuclear Iridium(III) Complex with a Bridging Disulfide Bond. Conversion of Coordinated Thiolato to Coordinated Bridging Disulfide by Acid Oxidation
• Heptacoordinate Vanadium(III) Complexes Containing a Didentate Sulfate Ligand. X-Ray Structures of [V_2(SO_4)_3{N, N'-bis(2-pyridylmethyl)-1, 2-ethanediamine}_2] and [V(SO_4){N, N, N', N'-tetrakis(2-pyridylmethyl)-1, 2-ethanediamine}]^+ and Their Solution
• Structures and Properties of Vanadium(III) Complexes with 1,2-Diaminoethane-N,N'-diacetate-N,N'-dipropionate and N, N-Bis(carboxymethyl)-β-alanate
• Syntheses, Characterization, and Properties of Vanadium(III) Complexes Containing Tripodal Tetradentate Ligands with Single Pyridyl Groups
• Preparation and Structure of Dinuclear Vanadium(III) Complex Triply Bridged by Three Different Groups
• Synthesis, Structure, and Magnetic Properth of a Dinuclear Vanadium(III) Complexes with N-Hydroxyethyliminodiacetate
• Preparation and Structure of Oxo-bridged Dinuclear Vanadium(III) Complex 〔V^_2(L-his)_4(μ-O〕・2H_2O
• Preparation and Structure of the Novel Dinuclear Vanadium(III) Complex Bridged by an Alkoxo Group and a Carboxylato Group
• Synthesis and Characterization of a Peroxovanadium (V) Complex Containing N-Carboxymethylhistidine as a Medel for the Vanadium Haloperoxidase Enzymes
• Gas Permeation Properties of Flexible Pyrolytic Membranes from Sulfornated Polyimides
• Novel Sulfoalkoxylated Polyimide Membrane for Polymer Electrolyte Fuel Cells
• Stereoselective Formation of[Cr(edda or eddp)(N-N)-Type Complexes with 1, 10-Phenanthroline(edda=ethylenediamine-N, N'-diacetate;eddp=ethylenediamine-N, N'-dipropionate)
• Novel Discrete Structure of Oxalate-bridged Heteronuclear Cr(III)-Nd(III)Complex
• Construction of the Tetranuclear Complex with Inter - and Intramolecular Stacking - Like Arrangement Composed of Planar Palladium (II) Units
• Novel S-Bridged Co^Pd^ Polynuclear Complexes Derived from [Ni^{(Co^(aet)_2(en)}_2]Cl_4 (aet=2-Aminoethanethiolate). Crystal Structures of [Pd{Co(aet)_2(en)}_2]Cl_4 and [PdCl_2{Co(aet)_2(en)}]Cl
• Synthesis, X-ray Structures, and Solution Properties of Vanadium(III) and -(IV) Complexes with N-(2-Hydroxyphenyl)-N-(2-pyridylmethyl)amine
• Preparations, Structures, and Properties of Sulfato-Bridged Dinuclear and Tetranuclear Vanadium(III) Complexes with a Dinucleating Ligand, 2-Oxo-N,N'-bis(2-pyridylmethyl)-1,3-propanediamine-N,N'-diacetate
• Tetranuclear Cobalt(III) Complex Having the Cubane Co_4O_4 Core: Synthesis and Structural Analysis of the Complex Containing (2-Pyridylmethyl)glycine
• Trinuclear Cobalt(III) Complex Having Partial Cubane Co_3O_4 Core : Synthesis and Structural Analysis of the Complex Containing Bis(2-pyridylmethyl)amine
• Trinuclear Cobalt(III) Complexes Containing Partial Cubane Co_3O_4 Core. Synthesis and Structure of [Co_3(L)_3(μ-OH)_3(μ_3-O)]Cl (L=ethylenediamine-N-acetate)
• Photochemistry of Cobalt(III) Complexes. I. Optically Active Cobalt(II) Complexes Containing Co-C Bond Prepared by Photodecarboxylation of Amino Carboxylato Complexes
• Double Sulfur Trans Influence in the Dithiolato Complex: trans(S)-[Co(aet)_2(en)]ClO_4(aet=2-Aminoethanetiolate)
• Field Emission Microscope Observations of H_2- and Metal-Phthalocyanines
• Synthesis, Structural Characterization, and Interconversion of S-Bridged Dinuclear and Hexanuclear Complexes Composed of cis(S)-[Co(aet)_2(en)]^+ and Trigonal-Bipyramidal Cadmium(II)(aet=2-Aminoethanethiolate, en=Ethylenediamine)
• Novel S-Bridged Tetranuclear Cobalt(III) Complexes with 2-Aminoethanethiolate Formed by Ligand Transfer from Nickel(II) to Cobalt(III)
• Synthesis and Properties of Linear-Type S-Bridged Rh^Ni^Rh^ Trinuclear Complexes with 2-Aminoethanethiolate (aet) or _L-Cysteinate (_L-cys). Crystal Structure of [Ni{Rh(aet)_3}_2](NO_3)_2
• Preparation and characterization of cobalt(III) complexes with S,S-bridge R,S-sexidentate-N2,S2,O2 type ligands. Crystal structure of (+)5C6D0-((2R,9S)-diamino-3,3,8,8-tetramethyl-4,7-dithia-1,10-decanedioato)cobalt(III) ion.
• Preparation and some properties of bis(trimethylenediamine)cobalt(III) complexes with a bidentate-N,S or -N,Se ligand.
• Characterization of cobalt(III) complexes with L-penicillaminate. Crystal structure of (diethylenetriamine)(L-penicillaminato)-cobalt(III) chloride monohydrate.
• Preparation and characterization of cobalt(III) complexes with L-cysteinate and S-methyl-L-cysteinate. Crystal structure of (L-cysteinato)(diethylenetriamine)cobalt(III) perchlorate.
• Preparation, structure, and circular dichroism spectra of [Co(L1)(L2)]+-type complexes (L1=iminodiacetato or N-methyliminodiacetato and L2=3-azapentane-1,5-diamine or 3-methyl-3-azapentane-1,5-diamine).
• Preparation and CD spectra of cobalt(III) complexes with S-(carboxymethyl)-L-cysteinate and its analogues.
• S-bridged polynuclear complexes. I Selective formation and crystal structure of (+)6C0D0-bis(tris(L-cysteinato-N,S)cobaltate(III)-.MU.-S,.MU.-S',.MU.-S")cobalt(III) nitrate pentahydrate.
• タイトル無し
• Raman spectral characteristics of (Co(ida)n(dien)2-n)-type and related complexes.
• Preparation and characterization of nickel(II) complexes with diethyl N,N'-ethylenebis(2-hydroxyimino-3-iminobutanoate) and its analogue.
• Preparation and spectroscopic studies of (diethylenetriamine)cobalt(III) complexes with L-penicillaminate or its derivative.
• Preparation, crystal structure, and stereochemical properties of {N,N'-ethylenebis(1,1,1-trifluoro-4-imino-2-pentanonato)} (L-methioninato)cobalt(III).
• Heterogeneous photocatalytic decomposition of phenol over TiO2 powder.
• Electrical dark- and photo-conductivities of 2-(p-decyloxybenzilideneamino)-9-fluorenone in the nematic state.
• Charge-carrier transport in nematic 2-(p-decyloxybenzylideneamino)-9-fluorenone.
• Preparation and spectral properties of cobalt(III) complexes with S,S'-ethylenebis(L-homocysteinate) and S,S'-trimethylenebis(L-homocysteinate).
• The pulse-photoconductivity of poly(N-vinylbenzocarbazole)s.
• Preparation and characterization of (iminodiacetato)cobalt(III) complexes with L-methioninate and S-methyl-L-cysteinate.
• The pulse-photoconductivity of poly(1-vinylpyrene)
• Characterization of trans(O)-N,N'-ethylenebis(S-methyl-L-cysteinato)cobalt(III) perchlorate and the absolute configuration of the complex determined by X-ray analysis.
• Structure and racemization of optically active mer-(3-azapentane-1,5-diamine or 3-methyl-3-azapentane-1,5-diamine)(ethylenediamine-N-acetato)cobalt(III) complexes.
• Kinetics of heterogeneous photocatalytic decomposition of phenol over anatase TiO2 powder.
• Impurity Effect on Domain Formation in a Nematic Liquid Crystal
• The photoconductivity of poly(N-vinylcarbazole). VII. The effect of the singlet and triplet quenchers on the photoconductivity.
• Emission spectra of the vinyl polymers with pendant benzocarbazolyl groups.
• Triplet excitation energy transfer in the vinyl polymers with pendant carbazolyl groups.
• Photoconductivity of Vinyl Polymers with Large Pendant π-Electron Systems. I. Poly-9-vinylacridine

もっと見る 閉じる

スポンサーリンク