Preparation and spectroscopic studies of (diethylenetriamine)cobalt(III) complexes with L-penicillaminate or its derivative.
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概要
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The (diethylenetriamine)(L-penicillaminato)cobalt(III) complex, [Co(L-pen)(dien)]<SUP>+</SUP>, was chromatographically separated into three isomers, <I>trans</I>(<I>N</I><SUB>i</SUB><I>N</I>), <I>trans</I>(<I>N</I><SUB>i</SUB><I>O</I>) and <I>trans</I>(<I>N</I><SUB>i</SUB><I>S</I>). Each of these gave a corresponding isomer of the (diethylenetriamine)(<I>S</I>-methyl-L-penicillaminato)cobalt(III) complex, [Co(L-smp)(dien)]<SUP>2+</SUP>, by the reaction with dimethyl sulfate. The (triammine)(<I>S</I>-methyl-L-penicillaminato)cobalt(III) complex was also derived from the corresponding L-pen complex, [Co(L-pen)(NH<SUB>3</SUB>)<SUB>3</SUB>]<SUP>+</SUP>. The absorption and CD spectra of the L-pen complexes were compared with those of the L-smp ones to specify the geometrical configurations. The L-pen complexes exhibited characteristic absorption behavior and CD spectra in the region of (14–30)×10<SUP>3</SUP> cm<SUP>−1</SUP>.
- 公益社団法人 日本化学会の論文
著者
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Einaga Hisahiko
Department Of Applied Chemistry Nagoya Institute Of Technology
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Okamoto Ken-ichi
Department Of Advanced Materials Science & Engineering Faculty Of Engineering Yamaguchi Universi
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Hidaka Jinsai
Department of Chemistry Faculty of Science Osaka University
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Wakayama Katsuhiko
Department of Chemistry, University of Tsukuba
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