Characterization of cobalt(III) complexes with L-penicillaminate. Crystal structure of (diethylenetriamine)(L-penicillaminato)-cobalt(III) chloride monohydrate.
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概要
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The crystal structure of the title complex, which was chromatographically obtained as the first eluted isomer, has been determined by the X-ray diffraction method. The dark-brown needle crystal was hexagonal, space group P6<SUB>1</SUB>, <I>a</I>=21.035(5), <I>c</I>=6.459(3) Å, <I>Z</I>=6, and the final <I>R</I> value was 0.076 for 1504 non-zero reflections. Of three possible isomers for the (diethylenetriamine)(L-penicillaminato)cobalt(III) complex, the complex isolated has <I>trans</I>(<I>N</I><SUB>1</SUB><I>N</I>) configuration. The average Co–N distance for the nitrogen atoms bonded <I>cis</I> to the sulfur atom is 1.961 Å, whereas the trans Co–N length is 2.007 Å.
- 公益社団法人 日本化学会の論文
著者
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Einaga Hisahiko
Institute Of Materials Science University Of Tsukuba
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Okamoto Ken-ichi
Department Of Advanced Materials Science & Engineering Faculty Of Engineering Yamaguchi Universi
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Hidaka Jinsai
Department of Chemistry Faculty of Science Osaka University
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Wakayama Katsuhiko
Department of Chemistry, University of Tsukuba
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Ohmasa Masaaki
Institute of Materials Science, University of Tsukuba
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