Crystal structure and absolute configuration of d-tartaric acid-(+)5C0D0-tris(2-aminoethanesulfenato)cobalt(III)-water (1/1/1).

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概要

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• The crystal structure and absolute configuration of diastereomeric molecular compound, <I>d</I>-C<SUB>4</SUB>H<SUB>6</SUB>O<SUB>6</SUB>·(+)<SUB>500</SUB><SUP>CD</SUP>[Co{S(O)CH<SUB>2</SUB>CH<SUB>2</SUB>NH<SUB>2</SUB>}<SUB>3</SUB>]·H<SUB>2</SUB>O, were determined by the X-ray diffraction method. The crystals are orthorhombic with space group P2<SUB>1</SUB>2<SUB>1</SUB>2<SUB>1</SUB>, <I>Z</I>=4, and <I>a</I>=13.034(4), <I>b</I>=13.559(6), and <I>c</I>=11.048(8) Å. The rifinement of 1724 reflections (Mo <I>K</I>α radiation) led to <I>R</I>=0.068. The complex molecule has the configuration <I>fac</I>(<I>S</I>)-<I>Λ</I>-(δ,δ,δ)-(<I>R</I>, <I>R</I>, <I>R</I>). All amino groups and the sulfenato oxygen atoms form hydrogen bonds with <I>d</I>-tartaric acid and/or water molecules three-dimensionally, which is responsible for the formation of the novel diastereomeric molecular compound.

• 公益社団法人 日本化学会の論文

著者

• Yamanari Kazuaki

  Department Of Chemisry Faculty Of Science Osaka University

• Shimura Yoichi

  Department of Chemistry Faculty of Science Osaka University

• Kita Masakazu

  Department of Chemistry, Faculty of Science, Nagoya University

• Kitahama Katsuki

  Department of Chemistry, Faculty of Science, Osaka University

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