Reaction of hydrogen atoms with acrylaldehyde.
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概要
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The reaction of hydrogen atoms with acrylaldehyde was investigated in a fast flow reactor equipped with a time-of-flight type mass spectrometer under reduced pressure. Main reaction products were carbon monoxide, ethylene, ethane, methane, and propanal. Consideration of the distributions of the reaction products under various reaction conditions showed that hydrogen atoms attacked the C=C double bond, especially its inner carbon side under reduced pressure. Resulting hot radicals caused subsequent reactions. The relative value of the apparent bimolecular rate constant of the reaction against that of <I>trans</I>-2-butene with hydrogen atoms was 1.6±0.2, which supported the above-mentioned initial reaction.
- 公益社団法人 日本化学会の論文
著者
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Koda Seiichiro
Department Of Chemical Engineering Facutly Of Engineering The University Of Tokyo
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Hoshino Takashi
Department Of Agricultural Chemistry Faculty Of Agriculture Tohoku University:(present Address)niiga
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Hikita Tsutomu
Department of Reaction Chemistry, Faculty of Engineering, The University of Tokyo
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Nakamura Kazumoto
Department of Reaction Chemistry, Faculty of Engineering, The University of Tokyo
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- Reaction of hydrogen atoms with acrylaldehyde.