Studies on the Extraction and Determination of Metal Salts with Methyl Isobutyl Ketone. XI : Extraction of Thallium
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概要
- 論文の詳細を見る
Liquid-liquid extraction of thallium (III) with methyl isobutyl ketone was studied, employing 10 ml of the solvent and 10 ml of an aqueous solution containing 10 mg of thallium and various mineral acids. The extraction rate was calculated from the amount of thallium salt remaining in the aqueous solution in equilibrium, determined by the oxine method or by photometry. Thallium (III) could be extracted with more than 99.8% recovery from 1.5〜8 N hydrochloric acid solutions. The addition of an adequate amount of nitric, sulfuric, or perchloric acid enhanced the extraction up to about 99% even in such a low concentration as 0.5 N hydrochloric acid solution. From the sulfuric acid solution at 8 N only about 21% thallium was extracted.
- 東北大学の論文
著者
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GOTO Hidehiro
The Research Institute for Iron, Steel and Other Metals
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Goto Hidehiro
The Research Institute For Iron Steel And Other Metal S
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KAKITA Yachiyo
The Research Institute for Iron, Steel and Other Metals
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ICHINOSE Norio
The Research Institute for Iron, Steel and Other Metals
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Kakita Yachiyo
The Research Institute For Iron Steel And Other Metals
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Ichinose Norio
The Research Institute For Iron Steel And Other Metals
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Goto Hidehiro
The Research Institute For Iron Steel And Other Metal
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