Sterically Constrained 'Roofed' 2-Thiazolidinones as Excellent Chiral Auxiliaries
スポンサーリンク
概要
- 論文の詳細を見る
The "roofed" chiral 2-thiazolidinones, which are sterically congested and conformational rigid, and which are perpared by the [4+2] cycloaddition of 2-thiazolone to the cyclic dienes, dimethylanthracene and hexamethylcyclopentadiene, followed by optical resolution with (1S, 2R)-2-methyoxy-1-apocamphanecarbonic acid (MAC acid) are of considerable promise for use as chiral auxiliaries for the alkylation of enolates.
- 公益社団法人日本薬学会の論文
- 2000-10-01
著者
-
KUNIEDA Takehisa
Faculty of Pharmaceutical Sciences, Sojo University
-
國枝 武久
Kumamoto Univ. Kumamoto Jpn
-
HOSHIMOTO Shigeki
Faculty of Pharmaceutical Sciences, Kumamoto University
-
MATSUNAGA Hirofumi
Faculty of Pharmaceutical Sciences, Kumamoto University
-
Matsunaga H
Takeda Chemical Ind. Ltd. Osaka Jpn
-
Hoshimoto S
Kumamoto Univ. Kumamoto Jpn
-
Kunieda Takehisa
Faculty Of Pharmaceutical Sciences Kumamoto University
-
Matsunaga H
Dep. Of Pharmacy Okayama Univ. Hospital
-
Matsunaga Hirofumi
Faculty of Life Sciences, Kumamoto University
関連論文
- A Highly Sensitive Enzyme-Linked Immunosorbent Assay (ELISA) for Antitumor Polyacetylenic Alcohol, Panaxytriol
- The First Specific Antibody against Cytotoxic Polyacetylenic Alcohol, Panaxynol
- Inhibitory Effect of cis-Dehydromatricaria Ester Isolated from Solidago altissima on the Growth of Mammalian Cells
- Cytotoxic Activity of Polyacetylene Compounds in Panax ginseng C. A. MEYER
- Studies on the Panaxytriol of Panax ginseng C. A. MEYER. Isolation, Determination and Antitumor Activity
- Antiproliferative Constituents from Umbelliferae Plants. V. A New Furanocoumarin and Falcarindiol Furanocoumarin Ethers from the Root of Angelica japonica
- Antiproliferative Constituents in Umbelliferae Plants. IV. Constituents in the Fruits of Anthriscus sylvestris HOFFM.
- Antiproliferative Constituents in Umbelliferae Plants. III. Constituents in the Root and the Ground Part of Anthriscus sylvestris HOFFM.
- Antiproliferative Constituents in Umbelliferae Plants II. : Screening for Polyacetylenes in Some Umbelliferae Plants, and Isolation of Panaxynol and Falcarindiol from the Root of Heracleum moellendorffii
- Structures and Antiproliferative Activity of Saponins from Sechium pittieri and S. talamancense
- Mechanism for Conversion of Spirosolane Derivative into Pregnane
- A Highly Sensitive ELISA for the Quantification of Polymyxin B Sulfate in Human Serum
- 60 2-オキサゾロンを構築材とする1、2-アミノアルコール類の効率合成(口頭発表の部)
- VERSATILE ROUTES TO CHIRAL 4-SUBSTITUTED 2-OXAZOLIDINONES AND α-AMINO ACIDS. USE OF CHIRON, [4+2] CYCLOADDUCTS OF DIALKYL AZODICARBOXYLATES AND 2-OXAZOLONES
- PB61 VERSATILE CHIRAL SYNTHONS FOR VIC-AMINO ALCOHOLS
- Highly Accelerating Effect of Lewis Acids on Ruthenium(II)-Catalyzed Radical Addition Reactions
- 複素五員環化合物を反応素子とする高度反応制御系の化学
- Sterically Constrained 'Roofed' 2-Thiazolidinones as Excellent Chiral Auxiliaries
- 奨励賞受賞 石塚忠男氏の業績
- 2-オキサゾロンを構築材とする2-アミノアルコール類のキラル合成
- 優美な液晶反応場への期待 : 液晶は反応を高度に制御できるか
- 高性能2-オキサゾリジノン系不斉補助剤の開発
- STERICALLY CONGESTED CHIRAL N-ACETYL 2-OXAZOLIDINONE AS ACETYL ENOLATE EQUIVALENTS IN STEREOSELECTIVE ALDOL REACTIONS
- よく使われるヘテロ環不斉補助剤
- 2-アミノアルコ-ル系キラル合成子の開発と応用
- Stereoselective Preparation of (1S, 2R)- and (1S, 2S)-2-Hydroxy-7,7-dimethylbicyclo[2.2.1]heptane-1-carboxylic Acids
- 液晶反応場の有機化学的利用 (有機合成の新しいトレンド)
- 複素環骨格の反応特性を利用する有機合成
- Sterically Congested, “Roofed” β-Iminodisulfides as New Chiral Ligands for Palladium-Catalyzed, Asymmetric Allylic Alkylation
- 2-アミノアルコール系キラル合成子の開発と応用
- 液晶反応場の有機化学的利用
- Chiral Functionalization of 2(3H)-Thiazolone. New Route to Chiral Synthons for 2-Amino Thiols
- Pratical Preparation of Chiral 4-Substituted 2-Oxazolidinones
- Synthetic Versatility of 2-Oxazolone Heterocycle for Stereo-controlled Construction of 2-Amino Alcohols
- A Simple, Iron-Catalyzed, Pyridine-Assisted Hydrogen Peroxide Epoxidation System
- Generation of Radical Species from Dihydropyrazines Having DNA Strand-Breakage Activity and Other Characteristics