液晶反応場の有機化学的利用
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概要
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Liquid crystals possessing properties intermediate to crystals and isotropic liquids potentially serve as anisotropic reaction-media, in which the reactivities of a variety of reactions are expected to be considerably different from those in the liquid and the solid state. This article briefly surveys unimolecular and bimolecular photo- and thermal reactions conducted in thermotropic liquid crystals, of which unique features are distinctly reflected on the reaction rates, efficiencies and stereochemical courses. Structural compatibility and orientational restriction are generally suggested to play a major role in controlling the reactivities by such ordered media.
- 社団法人 有機合成化学協会の論文
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