複素環骨格の反応特性を利用する有機合成
スポンサーリンク
概要
- 論文の詳細を見る
Synthetic potential of 4,5-unsubstituted 2-oxazolone heterocycle has been reviewed as a versatile building block for vic-amino alcohol structures found in a number of bioactive compounds as well as a promising leaving moiety in carboxyl and phosphoryl activation processes. Good versatile strategy from such a simple heterocycle to a wide variety of 1,2-amino alcohols is described and successfully applied to the efficient preparation of biologically significant hydroxy amino acids such as statine and hydroxyglutamic acid. The oxazolone-based compounds are introduced as excellent reagents for phosphorylation of alcohols and for β-lactam formation from β-amino acids.
- 公益社団法人日本薬学会の論文
- 1988-07-25
著者
関連論文
- 60 2-オキサゾロンを構築材とする1、2-アミノアルコール類の効率合成(口頭発表の部)
- VERSATILE ROUTES TO CHIRAL 4-SUBSTITUTED 2-OXAZOLIDINONES AND α-AMINO ACIDS. USE OF CHIRON, [4+2] CYCLOADDUCTS OF DIALKYL AZODICARBOXYLATES AND 2-OXAZOLONES
- Highly Accelerating Effect of Lewis Acids on Ruthenium(II)-Catalyzed Radical Addition Reactions
- 複素五員環化合物を反応素子とする高度反応制御系の化学
- Sterically Constrained 'Roofed' 2-Thiazolidinones as Excellent Chiral Auxiliaries
- 奨励賞受賞 石塚忠男氏の業績
- 2-オキサゾロンを構築材とする2-アミノアルコール類のキラル合成
- 優美な液晶反応場への期待 : 液晶は反応を高度に制御できるか
- 高性能2-オキサゾリジノン系不斉補助剤の開発
- STERICALLY CONGESTED CHIRAL N-ACETYL 2-OXAZOLIDINONE AS ACETYL ENOLATE EQUIVALENTS IN STEREOSELECTIVE ALDOL REACTIONS
- よく使われるヘテロ環不斉補助剤
- 2-アミノアルコ-ル系キラル合成子の開発と応用
- Stereoselective Preparation of (1S, 2R)- and (1S, 2S)-2-Hydroxy-7,7-dimethylbicyclo[2.2.1]heptane-1-carboxylic Acids
- 液晶反応場の有機化学的利用 (有機合成の新しいトレンド)
- 複素環骨格の反応特性を利用する有機合成
- 2-アミノアルコール系キラル合成子の開発と応用
- 液晶反応場の有機化学的利用