Studies on the Constituents of Calliandra anomala (KUNTH) MACBR. I. Structure Elucidation of Two Acylated Triterpenoidal Saponins

スポンサーリンク

概要

• 論文の詳細を見る

• Two novel triterpenoidal saponins, called calliandra saponins A and E, were isolated from the branches of Calliandra anomala (KUNTH) MACBR. On the basis of the chemical and physicochemical evidence, their structures were defined as 3-O-α-L-arabinopyranosyl-(1→2)-α-L-arabinopyranosyl-(1→6)-2-acetamido-2-deoxy-β-D-glucopyranosyl echinocystic acid 28-O-{β-D-glucopyranosyl-(1→3)-[β-D-xylopyranosyl-(1→3)-β-D-xylopyranosyl-(1→4)]-α-L-rhamnopyranosyl-(1→2)-[(6S)-2-trans-2,6-dimethyl-6-O-β-D-xylopyranosyl-2,7-octadienoyl-(1→6)]-β-D-glucopyranosyl} ester (4) and 3-O-α-L-arabinopyranosyl-(1→2)-α-L-arabinopyranosyl-(1→6)-2-acetamido-2-deoxy-β-D-glucopyranosyl echinocystic acid 28-O-{β-D-glucopyranosyl-(1→3)-[β-D-xylopyranosyl-(1→3)-β-D-xylopyranosyl-(1→4)]-α-L-rhamnopyransoyl-(1→2)-[(6'S)-2'-trans-2', 6'-dimethyl-6'-O-(2-O-(6S)-2-trans-2,6-dimethyl-6-hydroxy-2,7-octadienoyl)-β-D-xylopyranosyl-2', 7'-octadienoyl-(1→6)-β-D-glucopyranosyl} ester (5), respectively.

• 公益社団法人日本薬学会の論文
• 1993-12-15

著者

• 荻原 幸夫

  Faculty of Pharmaceutical Sciences, Nagoya City University

• 荻原 幸夫

  日本薬科大学漢方薬学科

• 高島 繁樹

  Faculty of Pharmacy, Meijo University

• 荻原 幸夫

  Faculty Of Pharmaceutical Sciences Nagoya City University

• 中村 高敏

  国立医薬品食品衛生研究所:医薬品医療機器総合機構

• 竹田 忠紘

  Faculty Of Pharmaceutical Sciences Nagoya City University

• 中村 高敏

  Faculty of Pharmaceutical Sciences

• 矢野 理

  Mitsui Pharmaceuticals, Inc.,

• 矢野 理

  Mitsui Pharmaceuticals Inc.

• 高島 繁樹

  Faculty Of Pharmaceutical Sciences Nagoya City University

• Takeda T

  Kyoritsu University Of Pharmacy

関連論文

• 9.Penicillium duclauxi Delacroixの代謝産物について
• Selective Induction of Cell Death in Cancer Cells by Gallic Acid
• Cytotoxic Activity of Bryonolic Acid Isolated from Transformed Hairy Roots of Trichosanthes kirilowii var. japonica
• II-A-6 漢方処方の解析(その 66) : "複方木鶏"構成生薬『胡桃樹皮』の成分研究
• RELATION BETWEEN MONOCYTES IN PERIPHERAL BLOOD AND DEVELOPMENT OF ATHEROSCLEROSIS IN HYPERCHOLESTEROLEMIC RABBITS
• HPLCによるモロヘイヤ (Corchorus olitorius) 及びその加工品中の Digitoxigenin 配糖体の分析
• 63(P29) モロヘイヤ(Corchorus olitorius)中の強心配糖体について(ポスター発表の部)
• モロヘイヤ種子中の主強心配糖体の同定,分析及び,マウスに対する経口毒性について
• 一般用漢方処方の使用実態調査AUR(Actual Use Research)およびAURを用いた加味逍遙散の特徴解析
• A New Coumarin Glucoside from Daphne arisanensis
• 種々の合成オリゴ糖の抗Lipid IV抗血清結合活性に対する阻害効果
• A New Prosapogenin from Hovenia Saponin D by Mild Alkaline Degradation(Pharmacognosy,Chemical)
• New Triterpenoids from the Leaves of Bupleurum rotundifolium L.
• Studies on the Constituents of Epimedium koreanum
• BRYONOLIC ACID PRODUCTION IN HAIRY ROOTS OF TRICHOSANTHES KIRILOWII MAX. VAR. JAPONICA KITAM. TRANSFORMED WITH AGROBACTERIUM RHIZOGENES AND ITS CYTOTOXIC ACTIVITY
• Inhibition of Adenosine 3', 5'-Cyclic Monophosphate Phosphodiesterase by Lignan Glucosides of Eucommia Bark
• 9 Flavoskyrinの構造について
• Polysaccharides of Lichen Symbionts
• Polysaccharides of Lichens and Fungi. VI. Antitumour Active Polysaccharides of Lichens of Stictaceae
• TOTAL SYNTHESIS OF OCTASACCHARIDE RELATED TO GLYCOSPHINGOLIPID FROM THE SPERMATOZOA OF BIVALVES
• Synthetic Studies on Oligosaccharide of a Glycolipid from the Spermatozoa of Bivalves. VII. The Synthesis of Di-, Tri-, Tetrasaccharides Related to Glycosphingolipid
• 一般用漢方処方のパイロット使用実態調査研究 AUR (Actual Use Research) 及び一般用漢方処方の見直しを図るための調査研究について
• 漢方四方山話
• Studies on the Structure of a Minor Polysaccharide from the Bark of Melia azadirachta
• Studies on the Structure of Polysaccharide from Tetragonia tetragonoides. I
• Further Studies on the Structure of Polysaccharides from the Bark of Melia azadirachta
• Studies on the Structure of Polysaccharides from the Bark of Melia azadirachta
• Studies on the Constituents of Xanthoceras sorbifolia BUNGE. II. Major Sapogenol and a Prosapogenin from the Fruits of Xanthoceras sorbifolia BUNGE
• A pea NTPase, PsAPY1, recognizes signal molecules from microorganisms
• Development and Application of an Enzyme Immunoassay for Karasurin A, an Effective Protein Component of Trichosanthes kirilowii MAX. var. japonicum KITAM.
• 2 菌類代謝産物の化学 : Rugulosin,Luteoskyrin,Rubroskyrinおよび関連化合物の研究
• Presence of Protein Polymorphism in Karasurin, an Abortifacient and Anti-tumor Protein, Identified with Physicochemical Properties
• The Complete Amino Acid Sequence of an Abortifacient Protein, Karasurin
• Synthetic Studies on Glycosphingolipids from Protostomia Phyla : Synthesis of Amphoteric Glycolipid Analogues from the Porcine Nematode, Ascaris suum
• Effect of Hachimijiogan, an Oriental Herbal Medicinal Mixture, on Experimental Amnesia in Mice
• Effects of Saikosaponin Metabolites on the Hemolysis of Red Blood Cells and Their Adsorbability on the Cell Membrane
• A New Pharmacological Testing Method : Different Effects of Levamisole and the Serum of Mice Orally Treated with Levamisole on Mitogenic Activity of Lipopolysaccharide
• Peptides in Higher Plants. II. The Crystal Structure of Tri-N-methylfrangulanine Methiodide
• Metabolic Products of Fungi. XXIII. On Ustilaginoidins. (3). The Structures of Ustilaginoidins B and C.
• Ardisimamillosides G and H, Two New Triterpenoid Saponins from Ardisia mamillata
• Toxic Shock Syndrome and Pharmacokinetics of Vancomycin.
• 伝統医薬の創造的継承
• Studies on the Constituents of Calliandra anomala (KUNTH) MACBR. II. Structure Elucidation of Four Acylated Triterpenoidal Saponins
• Studies on the Constituents of Calliandra anomala (KUNTH) MACBR. I. Structure Elucidation of Two Acylated Triterpenoidal Saponins
• Studies on the Constituents of Apocynaceae Plants. Gas Chromatography-Mass Spectrometric Determination of New Flavonoid Triglycosides from the Leaves of Cerbera manghas L. (2)
• ALKALINE CLEAVAGE OF GINSENOSIDES(Communications to the Editor)
• Triterpenoid Glycosides from the Roots of Tetrapanax papyriferum K. KOCH. III. Structures of Four New Saponins
• Minor Triterpenoid Saponins from the Leaves of Bupleurum rotundifolium L.
• Studies on the Constituents of Xanthoceras sorbifolia BUNGE. III. Minor Prosapogenins from the Fruits of Xanthoceras sorbifolia BUNGE
• Polysaccharides of Lichens and Fungi. V. Antitumour Active Polysaccharides of Lichens of Evernia, Acroscyphus and Alectoria spp.
• Polysaccharides in Lichens and Fungi. III. Further Investigation on the Structures and the Antitumor Activity of the Polysaccharides from Gyrophora esculenta MIYOSHI and Lasallia papulosa LLANO
• Studies on the Chemical Structures of the New Glucans isolated from Gyrophora esculenta MIYOSHI and Lasallia papulosa (ACH.) LLANO and Their Inhibiting Effect on Implanted Sarcoma 180 in Mice
• Response of Liver to Glucocorticoid is Altered by Administration of Schosaikoto : Kampo Medicine
• Modification of Macrophage Functions by Shosaikoto (Kampo Medicine) Leads to Enhancement of Immune Response
• Sulfated Triterpenoid Saponins from the Leaves of Bupleurum rotundifolium L.
• Studies on the Constituents of Lindera erythrocarpa MAKINO. III. The Isolation and Crystal Structure of Sodium Lucidonate
• A binding protein for fungal signal molecules in the cell wall of Pisum sativum
• Peptides in Higher Plants. I. The Conformation of Frangulanine
• 14 EBELIN LACTONE形成サポニンの真正サポゲニンについて
• Five New Triterpenoid Saponins from the Roots of Platycodon grandiflorum
• Synthetic Studies on Glycosphingolipids from Protostomia Phyla : Synthesis of Amphoteric Glycolipid Analogues Containing a Phosphocholine Residue from the Earthworm Pheretima hilgendorfi
• The Nephritogenic Glycopeptide from Rat Glomerular Basement Membrane. II. Synthesis of O-(α-D-glucopyranosyl)-(1→6)-O-β-D-glucopyranosyl-(1→6)-N-(L-β-aspartyl)-α-D-glucopyranosylamine (α-D-Glc-(1→6)-β-D-Glc-(1→6)-α-D-Glc-(1→Asn))
• Syntheses of New Model Compounds Related to an Antigenic Epitope from Bupleurum falcatum L. and Their Distributions in Various Ganglioside-Phospholipid Monolayers
• Syntheses of Model Compounds Related to an Antigenic Epitope in Pectic Polysaccharides from Bupleurum falcatum L. (II)
• Phosphonoglycolipids in Marine Crustacean : Structural Characterization of Two Novel Phosphonocerebrosides, from the Crab, Erimacrus isenbeckii
• Effects of Oligosaccharides Having the Glucuronic Acid Residue on Base-Catalyzed Prostaglandin E_2 Dehydration and Isomerization
• Structural Characterization of a Novel Series of Fucolipids from the Marine Annelid, Pseudopotamilla occelata
• New Triterpenoid Glycosides from the Leaves of Bupleurum rotundi folium L.
• A New α-Glucan from the Lichen Parmelia caperata (L.) ACH.
• New A-Ring Lactone Triterpenoid Saponins from the Roots of Platycodon grandiflorum
• Studies on the chemical constituents from the roots of Platycodon grandiflorum
• β_1-Adrenergic receptor mediation in the lichen glucan PB-2-induced enhancement of long-term potentiation in the rat dentate gyrus in vivo
• Further Studies on the Structure of Polysaccharides from the Lichen Flavoparmelia caperata (L.) HALE
• Syntheses of Derivatives of the Trisaccharide GlcNAcβ1→2Manα1→3Man
• Polysaccharides in Lichens and Fungi. I. Antitumour Active Polysaccharides of Gyrophora esculenta MIYOSHI and Lasallia papulosa (ACH.) LANO
• On Methylphenylnaphthalenes. I. Syntheses of Methylphenylnaphthalenes.
• Expression of the 12-Oxophytodienoic Acid 10,11-Reductase Gene in the Compatible Interaction between Pea and Fungal Pathogen
• Two New Diterpenoids from Plectranthus nummularius BRIQ.
• THE NEPHARITOGENIC GLYCOPEPTIDE FROM RAT GLOMERULAR BASEMENT MEMBRANE. XI.TOTAL SYNTHESIS OF NEPHRITOGENOSIDE
• The Nephritogenic Glycopeptide from Rat Glomerular Basement Membrane. X. Synthesis of an N-Triglycosyl Dipeptide and Characteristics of Its cis-trans Isomers
• Metabolic Products of Fungi. XXII. On Ustilaginoidins. (2). The Structure of Ustilaginoidin A.
• Metabolic Products of Fungi. XXI. On Ustilaginoidins. (1). The Reactions of Ustilaginoidin A.
• 9.稲麹(Claviceps virens)の色素,Ustilaginoidin,の構造について
• 薬学研究者としての漢方への思い
• 病窓雑感
• Studies on the Structure of Polysaccharide from Trichophyton mentagrophytes
• The Structure of Nephritogenoside
• Selective Cleavage of the Amido Linkage of Glucopyranosylamine Derivatives by Ion-Exchange Resin Treatment
• Metabolic Products of Fungi. XXVIII. The Structure of Aurofusarin. (1)
• Studies on the Constituents of Xanthoceras sorbifolia BUNGE. V. Major Saponins from the Fruits of Xanthoceras sorbifolia BUNGE
• Isolation and Characterization of a New Abortifacient Protein, Karasurin, from Root Tubers of Trichosanthes kirilowii MAX. var. japonicum KITAM.
• ブシ及びブシ含有漢方製剤、生薬製剤中のアコニチン系アルカロイドの定量
• Studies on the Constituents of Anaxagorea luzonensis A. GRAY III
• Studies on the Constituents ofAnaxagorea luzonensis A. GRAY II(Natural Medicine Note)
• Metabolic Products of Fungi. XXX The Structure of Fuscofusarin
• Metabolic Products of Fungi. XXIX. The Structure of Aurofusarin. (2)
• インドセンダンの樹皮から得られる水溶性多糖体の研究(第3報)
• Synthesis of Methyl 2,3-, 2,4- and 3,4-Di-O-Methyl-α-D-Fucopyranosides
• Studies on the Constituents of Enkianthus nudipes. V. A New Lignan Xyloside from the Stems
• THE STRUCTURE OF NEPHRITOGENOSIDE

もっと見る 閉じる

スポンサーリンク