Synthesis of 2β-Hydroxycholecalciferol [2β-OH-D_3]
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概要
- 論文の詳細を見る
As part of a general exploration of the structure/activity relationships of the vitamin D system, the 2β-hydroxylated analogue of cholecalciferol (vitamin D_3) has been prepared from 2β-hydroxy-7-dehydrocholesterol obtained in our previous work as starting material via (i) photochemical conrotatory opening (2 N_f pericyclic reaction) of the B-ring and (ii) thermal 1,7-antarafacial hydrogen shift (3 N_f pericyclic reaction).
- 社団法人日本薬学会の論文
- 1975-07-25
著者
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金子 主税
東京医科歯科大歯 生化学
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石川 正幸
Division of Chemistry, Research Institute for Medical Engineering, Tokyo Medical and Dental Universi
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石川 正幸
Research Institute For Medical And Dental Engineering Tokyo Medical And Dental University
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石川 正幸
Institute For Medical And Dental Engineering Tokyo Medical And Dental University
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杉本 昭子
Institute For Medical And Dental Engineering Tokyo Medical And Dental University
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金子 主税
Division of Chemistry, Research Institute for Medical and Dental Engineering, Tokyo Medical and Dent
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山田 幸子
Division of Chemistry, Research Institute for Medical and Dental Engineering, Tokyo Medical and Dent
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SUGIMOTO AKIKO
Division of Chemistry, Research Institute for Medical and Dental Engineering, Tokyo Medical and Dent
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