Photochemistry of the N-Oxides of Azanaphthalene and Their Substituted Derivatives
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概要
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As previously reported, three rearrangement products were obtained on irradiation of quinaldine 1-oxide in methanol solution. To investigate the scope and further clarification of the mechanism of this rearrangement, the reaction has been extended to a variety of substituted azanaphthalene N-oxides and some phenanthridine N-oxides. The results obtained seem to support the postulated mechanism, namely, the photochemical formation of a three-membered ring intermediate (such as IV in the case of quinoline 1-oxides) and its subsequent thermal rearrangement to the final products.
- 公益社団法人日本薬学会の論文
- 1966-10-25
著者
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金子 主税
東京医科歯科大歯 生化学
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石川 正幸
Research Institute For Medical And Dental Engineering Tokyo Medical And Dental University
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金子 主税
Research Institute for Medical Engineering, Tokyo Medical and Dental University
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山田 幸子
Research Institute for Medical Engineering, Tokyo Medico-Dental University
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堀田 弘道
Research Institute of Dental Materials, Tokyo Medical and Dental University
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堀田 弘道
Research Institute Of Dental Materials Tokyo Medical And Dental University
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