Total Synthesis of (+)-(2S, 3R)-Piscidic Acid via Catalytic Asymmetric Dihydroxylation of a Trisubstituted Olefin
スポンサーリンク
概要
- 論文の詳細を見る
(+)-(2S, 3R)-Piscidic acid was efficiently synthesized with high optical purity (90% e.e.) via Sharpless catalytic asymmetric dihydroxylation of a trisubstituted olefin in only 6 steps from commercially available 4-hydroxyphenyl-pyruvic acid as the starting material. The reaction proceeded with high optical purity by using the chiral ligands, dihydroquinidine 2,5-diphenyl-4,6-pyrimidinediyl diether or dihydroquinidine 1,4-anthraquinonediyl diether.
- 社団法人日本農芸化学会の論文
- 1999-05-23
著者
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吉原 照彦
北海道支部
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吉原 照彦
北大農
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Saito Minoru
Division Of Cellular & Molecular Toxicology National Institute Of Health Sciences
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Saito Masako
Department Of Applied Physics University Of Tokyo:(present Address)institute For Solid State Physics
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TOSHIMA Hiroaki
Department of Bioresource Science, College of Agriculture, Ibaraki University
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YOSHIHARA Teruhiko
Department of Bioscience and Chemistry, Faculty of Agriculture, Hokkaido University
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Saito M
Department Of Biotechnology And Life Science Tokyo University Of Agriculture And Technology
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SATO Michio
Div. of Medical Devices National Institute of Hygienic Sciences
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SAITO MASATOSHI
Department of Obstetrics and Gynecology, Tohoku University Graduate School of Medicine
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吉原 照彦
Laboratory Of Bio-organic Chemistry Division Of Applied Bioscience Graduate School Of Agriculture Ho
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Yoshihara Teruhiko
Department Of Agricultural Chemistry Faculty Of Agriculture Hokkaido University
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Sugi M
Toin Univ. Yokohama Yokohama Jpn
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Toshima H
Department Of Bioresource Science College Of Agriculture Ibaraki University
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Toshima Hiroaki
Department Of Applied Bioscience Graduate School Of Agriculture Hokkaido University
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Shigeno M
Sii Nanotechnology Inc.
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Yokoyama T
Laboratory Of Bio-organic Chemistry Division Of Applied Bioscience Graduate School Of Agriculture Ho
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Saito Masatoshi
Department Of Fine Materials Engineering Faculty Of Textile Science And Technology Shinshu Universit
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