Processing and Properties of Rare Earth Ion-Doped Bismuth Titanate Thin Films by Chemical Solution Deposition method
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概要
- 論文の詳細を見る
Ferroelectric (Bi,R)4Ti3O12 [R: rare earth] thin films were synthesized by the chemical solution deposition (CSD) method. Heat treatment above 600°C was required for the fabrication of crystalline (Bi,R)4Ti3O12 thin films of Bi-layered perovskite structure on Pt/TiOx/SiO2/Si substrates. The orientation of the films prepared at 750°C depended upon the kind of substituent rare earth ions. Bi4.12Ti3O12 (BIT) and Bi3.35La0.75Ti3O12 (BLT) thin films revealed ($00l$) preferred orientation. On the other hand, Bi3.35Nd0.75Ti3O12 (BNT), Bi3.35Sm0.75Ti3O12 (BST) and Bi3.35Gd0.75Ti3O12 (BGT) thin films showed random orientation with strong (117) reflection. Synthesized (Bi,R)4Ti3O12 films exhibited the typical ferroelectric behavior. The BNT thin film showed $P_{\text{r}}$ of 21.6 μC/cm2, which was higher than the values of the other rare earth-doped BIT thin films.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2003-08-15
著者
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YOGO toshinobu
Center for Integrated Research in Science and Engineering, Nagoya University
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Yamada Mio
Department Of Applied Chemistry Graduate School Of Engineering Nagoya University
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Kikuta Koichi
Department Of Applied Chemistry Graduate School Of Engineering Nagoya University
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Hirano Shin-ichi
Department Of Applied Chemistry Graduate School Of Engineering Nagoya University
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Yamaguchi Toshiaki
Department Of Anesthesiology Yamanashi Medical University
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Sakamoto Wataru
Center For Integrated Research In Science And Engineering Nagoya University
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Hayashi Takashi
Department Of Applied Chemistry Graduate School Of Engineering Osaka University
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Iizawa Naoya
Department of Materials Science, Shonan Institute of Technology, 1-1-25 Tsujido-Nishikaigan, Fujisawa, Kanagawa 251-8511, Japan
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Iizawa Naoya
Department of Material Science and Engineering, Shonan Institute of Technology
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Yogo Toshinobu
Center for Integrated Research in Science and Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan
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