Second Harmonic Generation of Thermally Poled ZnCl2–B2O3–TeO2 Glasses and Its Mechanism
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概要
- 論文の詳細を見る
Second harmonic generation (SHG) was observed from halide, in particular, chlorine-containing glasses. The magnitude of SHG increased with increasing ZnCl2 concentration and poling time. Although the mechanism of SHG is still controversial, the deficiency of cations near the anode surface was detected. However, in this glass system, the polishing of the anode side showed no effect on SHG. However, the polishing of the cathode side significantly decreased the magnitude of SHG. Therefore, the SHG mechanism in this glass system is made evident for the first time in which the movement of anions resulting in an anion-deficient layer near the cathode side is able to cause SHG.
- 2005-07-10
著者
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Kamiya Kanichi
Department Of Chemistry For Materials Faculty Of Engineering Mie University
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Nasu Hiroyuki
Department Of Chemistry For Materials Faculty Of Engineering Mie University
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Takeda Hirofumi
Department Of Chemistry For Materials Faculty Of Engineering Mie University
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Nagaike Yuki
Department Of Chemistry For Materials Faculty Of Engineering Mie University
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Hashimoto Tadanori
Department Of Chemistry For Materials Faculty Of Engineering Mie University
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Nasu Hiroyuki
Department of Chemistry for Materials, Faculty of Engineering, Mie University, 1577 Kurimamachiya-machi, Tsu 514-8507, Japan
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Nagaike Yuki
Department of Chemistry for Materials, Faculty of Engineering, Mie University, 1577 Kurimamachiya-machi, Tsu 514-8507, Japan
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Hashimoto Tadanori
Department of Chemistry for Materials, Faculty of Engineering, Mie University, 1577 Kurimamachiya-machi, Tsu 514-8507, Japan
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