The .SIGMA.-bonded palladium(II) complexes of 2-aryl-4,4-dimethyl-2-oxazolines.
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概要
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Reactions of 2-phenyl-4,4-dimethyl-2-oxazoline with lithium tetrachloropalladate(II) and palladium(II) acetate give dichlorobis(2-phenyl-4,4-dimethyl-2-oxazoline,3-<I>N</I>)palladium(II) and a cyclopalladated binuclear complex, di-μ-acetato-bis[2-(4′,4′-dimethyl-2′-oxazolinyl)phenyl,1-<I>C</I>,3′-<I>N</I>)dipalladium(II), respectively. The latter complex is readily converted by a metathetical reaction with lithium chloride into its chloro-bridged analogue. The chloro-bridged complex reacts with triphenylphosphine to give the corresponding mononuclear σ-bonding palladium complex. All the complexes prepared in this study were characterized by means of IR and NMR spectroscopies.
- 公益社団法人 日本化学会の論文
著者
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Kasahara Akira
Department Of Applied Chemistry Faculty Of Engineering
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Watabe Hiroyuki
Department Of Biochemistry Faculty Of Pharmaceutical Sciences Health Sciences University Of Hokkaido
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Izumi Takeo
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Watabe Hiroyuki
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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