Synthesis of paracyclo(1,8)napthalenophane and paracyclo(5,6)acenaphthenophane.
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概要
- 論文の詳細を見る
[2]Paracyclo[2]paracyclo[2](1,8)naphthalenophan-9-ene-1,17-diyne, [0]paracyclo[2]paracyclo[0](5,6)acenaphthenophan-7-ene, and [2]paracyclo[2]paracyclo[2](5,6)acenaphthenophan-9-ene-1,17-diyne, were synthesized by intramolecular reductive coupling reaction of the corresponding carbonyl compounds with low-valent titanium reagent. The structures of the compounds were elucidated by NMR analyses, and the transannular π-electronic interactions between two benzene rings were examined on the basis of electronic spectra.
- 公益社団法人 日本化学会の論文
著者
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Kasahara Akira
Department Of Applied Chemistry Faculty Of Engineering
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Izumi Taeko
Department Of Applied Chemistry Faculty Of Engineering
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Satou Masahiro
Department Of Biomolecular Functional Engineering College Of Engineering Ibaraki University
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Shimizu Iwao
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Katou Takao
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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