The .SIGMA.-bonded palladium(II) complex of (dimethylaminomethyl)ruthenocene.
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概要
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The reaction between (dimethylaminomethyl)ruthenocene with lithium tetrachloropalladate(II) in the presence of sodium acetate gave di-μ-chloro-bis[2-(dimethylaminomethyl)ruthenocenyl]dipalladium(II) (<B>2</B>). The σ-bonded structure of <B>2</B> has been confirmed by IR analysis and the reactions of <B>2</B> with triphenylphosphine, thallium(I) acetylacetonate, and lithium aluminum deuteride. The reactions of chloro [2-(dimethylaminomethyl)ruthenocenyl](triphenylphosphine)palladium(II) with carbon monoxide and <B>2</B> with methyl vinyl ketone, phenyl vinyl ketone, and styrene have been examined. 1,2-Disubstituted ruthenocene derivatives have been obtained in higher yields than those of the corresponding ferrocene derivatives.
- 公益社団法人 日本化学会の論文
著者
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Kasahara Akira
Department Of Applied Chemistry Faculty Of Engineering
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Izumi Taeko
Department Of Applied Chemistry Faculty Of Engineering
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Kimura Tetsuo
Government Industrial Research Institute, Tohoku
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Kamiyama Shin-ichi
Government Industrial Research Institute
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Maemura Mitsugi
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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