A palladium-catalyzed alkoxycarbonylation of ethynylmercury compounds.
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概要
- 論文の詳細を見る
Bis(phenylethynyl)mercury reacts with carbon monoxide and alcohol at room temperature in the presence of palladium(II) salt to form dialkyl phenylmaleate, accompanied by small amounts of alkyl phenylpropiolate and dialkyl phenylfumarate. An alkoxycarbonylation at 100 °C afforded a trialkoxycarbonylation product, accompanied by dialkoxycarbonylation products. The alkoxycarbonylation of bis(ethylethynyl)mercury proceeds similarly.
- 公益社団法人 日本化学会の論文
著者
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Kasahara Akira
Department Of Applied Chemistry Faculty Of Engineering
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Izumi Taeko
Department Of Applied Chemistry Faculty Of Engineering
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Suzuki Akio
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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