Preparation and complexing properties of crown ether compounds incorporating a ferrocene unit at 1,2- or 1,3-positions.
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概要
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Ten new crown ethers incorporating a ferrocene unit at 1,2- or 1,3-positions are reported. These crown ethers were synthesized by the reaction of 1,2- or 1,3-bis(hydroxymethyl)ferrocene with oligoethylene glycol ditosylate (<I>n</I>=1–5) with potassium <I>t</I>-butoxide by a high-dilution method. These new types of ferrocene crown ethers were examined for complexation behavior with alkali, alkaline earth, and transition-metal cations by solvent extraction. It was found to extract thallium ions most effectively.
- 公益社団法人 日本化学会の論文
著者
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Kasahara Akira
Department Of Applied Chemistry Faculty Of Engineering
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Izumi Taeko
Department Of Applied Chemistry Faculty Of Engineering
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Matsunaga Shigeki
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Saitou Katsuo
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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