Synthesis of (3.3)(1,3)ferrocenophane and its derivatives.
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概要
- 論文の詳細を見る
[3.3](1,3)Ferrocenophane-1,15-diene-3,14-dione was synthesized <I>via</I> the base-catalyzed condensation of 1,3-ferrocenedicarbaldehyde with 1,3-diacetylferrocene utilizing the high dilution technique. The reduction of the compound with LiAlH<SUB>4</SUB>–AlCl<SUB>3</SUB> and the subsequent catalytic hydrogenation led to the formation of [3.3](1,3)ferrocenophane. The transannular π-electronic interactions between the two ferrocene moieties in these compounds were examined on the basis of NMR and electronic spectra.
- 公益社団法人 日本化学会の論文
著者
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Kasahara Akira
Department Of Applied Chemistry Faculty Of Engineering
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Izumi Taeko
Department Of Applied Chemistry Faculty Of Engineering
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Yoshida Yoshio
Department Of Biology Faculty Of Science Niigata University
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Shimizu Iwao
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Yoshida Yoshio
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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