The .SIGMA.-bonded palladium(II) complex of (.PI.-(dimethylaminomethyl)cyclopentadienyl)tetraphenylcyclobutadienecobalt(I).
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概要
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[π-(Dimethylaminomethyl)cyclopentadienyl]tetraphenylcyclobutadienecobalt(I) reacts with lithium tetrachloropalladate(II) in the presence of sodium acetate to give an ortho-palladated binuclear complex. The σ-bonded structure of the complex was confirmed by studies of the IR and <SUP>1</SUP>H-NMR spectra and of the reactions with triphenylphosphine, thallium(I) acetylacetonate, and lithium aluminum deuteride. The reactions of the σ-bonded complex with carbon monoxide and olefins have been examined.
- 公益社団法人 日本化学会の論文
著者
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Kasahara Akira
Department Of Applied Chemistry Faculty Of Engineering
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Izumi Taeko
Department Of Applied Chemistry Faculty Of Engineering
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Oikawa Tadashi
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Maemura Mitsugi
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Endoh Kazuyoshi
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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Zakozi Satoshi
Department of Applied Chemistry, Faculty of Engineering, Yamagata University
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