Electrochemical properties of ferrocenophanes. I. Voltammetric studies on the oxidation of mono-, di-, and tri-bridged ferrocenophanes in acetonitrile.

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概要

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• Electrode reactions of mono-, di- and tri-bridged ferrocenophanes ([3]Fcp, [4]Fcp, [3][3]Fcp, [4][3]Fcp, [4][4]Fcp, [3][3][3]Fcp, [4][4][3]Fcp and [4][4][4]Fcp) in acetonitrile were investigated by direct current polarography, pulse polarography, and cyclic voltammetry. The oxidation of these compounds proceeds reversibly as a one-electron process. The linear relationship between the half-wave potential and the number of methylene groups was obtained for ferrocene and ferrocenophanes other than [3][3]Fcp and [3][3][3]Fcp. The Taft substituent constants of trimethylene and tetramethylene groups were estimated.

• 公益社団法人 日本化学会の論文

著者

• Kasahara Akira

  Department Of Applied Chemistry Faculty Of Engineering

• Izumi Taeko

  Department Of Applied Chemistry Faculty Of Engineering

• Ogata Tateaki

  Department Of Chemistry And Chemical Engineering Faculty Of Engineering Yamagata University

• Tanaka Nobuyuki

  Department Of Botany Kochi Prefectural Makino Botanical Garden

• Fujisawa Tadashi

  Department of Environmental Chemistry, Yamagata Technical College

• Oikawa Kazuo

  Department of Environmental Chemistry, Yamagata Technical College

• Motoyama Shunsuke

  Department of Applied Chemistry, Faculty of Engineering, Yamagata University

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