Temperature and isotope effects in the reactions of phenylcarbene with acetone.
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概要
- 論文の詳細を見る
Phenylcarbene generated in acetone solution gives oxirane, vinyl ether and 1,3-dioxolane presumably <I>via</I> initial attack of the singlet state on the lone pair electrons of carbonyl oxygen leading to a carbonyl ylide, whereas a C–H insertion product arising from the triplet markedly increases in matrix environments.
- 公益社団法人 日本化学会の論文
著者
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Izawa Yasuji
Department Of Applied Chemistry Aichi Institute Of Technology
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Tomioka Hideo
Department Of Applied Chemistry Aichi Institute Of Technology
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Nakamura Hiroyuki
Department of Advanced Materials, University of Tokyo, Kashiwa, Chiba 277-8561
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Izawa Yasuji
Department of Industrial Chemistry, Faculty of Engineering, Mie University
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Ozaki Yasuji
Department of Industrial Chemistry, Faculty of Engineering, Mie University
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Nakamura Hiroyuki
Department of Industrial Chemistry, Faculty of Engineering, Mie University
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