Effect of aryl substituents on 2-aryl-1,4,5,6,7,7-hexachloronorbornadiene-quadricyclane reversible isomerization.
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概要
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2-Arylhexachloronorbornadiene undergoes photoisomerization to the corresponding quadricyclane, which returns back to the norbornadiene upon heating without catalyst. Effect of aryl substituents on the thermal reversion suggests that both spin delocalization and polar effect equally contribute to the stabilization of the transition state.
- 公益社団法人 日本化学会の論文
著者
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Izawa Yasuji
Department Of Applied Chemistry Aichi Institute Of Technology
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Tomioka Hideo
Department Of Applied Chemistry Aichi Institute Of Technology
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Hamano Yukinobu
Department of Industrial Chemistry, Faculty of Engineering, Mie University
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