Photoinduced alcoholysis of trihaloacetyl group.
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概要
- 論文の詳細を見る
Photolysis of trichloroacetamide in nondegassed methanol gave methyl oxanilate (13–44%), along with carbamate (3–20%) and amine (4–12%). Similar irradiation of other trichloroacetyl derivatives of aliphatic ketone, aldehyde, and acetate afforded only radical product. The results are interpreted in terms of the mechanism involving electron transfer of the radical pair.
- 公益社団法人 日本化学会の論文
著者
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Izawa Yasuji
Department Of Applied Chemistry Aichi Institute Of Technology
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Tomioka Hideo
Department Of Applied Chemistry Aichi Institute Of Technology
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Ishiguro Katsuhiro
Department of Industrial Chemistry, Faculty of Engineering, Mie University
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