Mechanism of the photochemical and thermal Wolff rearrangement of 2-diazo-1,3-dicarbonyl compounds.
スポンサーリンク
概要
- 論文の詳細を見る
Thermolysis and photolysis of 2-diazo-1,3-dicarbonyl compounds were investigated as a function of methanol concentration. As the methanol concentration decreased, methyl group migration increased concomitant with the suppression of O–H insertion into methanol, whereas aryl group migration was essentially unaltered with the methanol concentration. The results are interpreted as indicating that aryl migration occurs directly from the excited state of diazo compounds, but that met hyl migration takes place in the singlet carbene in competition with O–H insertion.
- 公益社団法人 日本化学会の論文
著者
-
Izawa Yasuji
Department Of Applied Chemistry Aichi Institute Of Technology
-
Tomioka Hideo
Department Of Applied Chemistry Aichi Institute Of Technology
-
Hayashi Norihiro
Department Of Clinical Pharmacology And Pharmacogenomics Graduate School Of Pharmaceutical Sciences Osaka University
-
Asano Tsuneo
Department of Industrial Chemistry, Faculty of Engineering, Mie University
-
Hayashi Norihiro
Department of Industrial Chemistry, Faculty of Engineering, Mie University
関連論文
- Prevention of osteoporosis by angiotensin-converting enzyme inhibitor in spontaneous hypertensive rats
- OE-071 A Genom-Wide Association Study of SNPs in the risk of Atherosclerosis Obliterans(Heart failure, clinical(01)(M),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- 日本人におけるGSTT1及びGSTM1の遺伝子多型の同定及びハプロタイプ構造の解析
- Genetic Variations of VDR/NR1I1 Encoding Vitamin D Receptor in a Japanese Population
- PJ-569 Long-term Results of Autologous Transplantation of Bone Marrow Mononuclear Cells for Patients with Thromboangiitis Obliterans(Peripheral circulation-6 (H) PJ96,Poster Session (Japanese),The 70th Anniversary Annual Scientific Meeting of the Japanese
- Renal Protective Effect in Hypertensive Patients : The High Doses of Angiotensin II Receptor Blocker (HARB) Study
- Renal-Protective Effect of T- and L-Type Calcium Channel Blockers in Hypertensive Patients : An Amlodipine-to-Benidipine Changeover (ABC) Study
- 3 Potential for Destination Therapy with Next Generation Left Ventricular Assist System (LVAS)(Impacts of latest developments of artificial organs/systems in the treatment of cardiovascular diseases,Topic 5 (TP-5) (IHD),Special Program,The 72nd Annual Sci
- Genetic Analysis of Young Adult Patients With Aortic Disease Not Fulfilling the Diagnostic Criteria for Marfan Syndrome
- OJ-247 New Genetic Disorders in the Patients with Aortic Disease(OJ42,Peripheral Circulation/Vascular Disease (Pathophysiology, Basic) (H),Oral Presentation (Japanese),The 73rd Annual Scientific Meeting of The Japanese Circulation Society)
- PJ-161 Clinical and Genetic Features of Marfan-Like Connective Tissue Disorders(Peripheral circulation/Vascular disease(06)(H),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- OJ-084 Ethnic Differences of Phenotypic manifestation of Marfan syndrome(Peripheral circulation/Vascular disease(02)(H),Oral Presentation(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- Phenotypic Heterogeneity of Marfan-Like Connective Tissue Disorders Associated With Mutations in the Transforming Growth Factor-β Receptor Genes
- Variation in OSBPL10 is associated with dyslipidemia
- 電気光学効果電界計測法における光学素子軸角選定による信号増幅
- Genetic Variations of CYP2C9 in 724 Japanese Individuals and Their Impact on the Antihypertensive Effects of Losartan
- Associations of Hypertension and Its Complications with Variations in the Xanthine Dehydrogenase Gene
- Clinical Usefulness and Limitations of Brachial-Ankle Pulse Wave Velocity in the Evaluation of Cardiovascular Complications in Hypertensive Patients
- Evaluation of Morning Blood Pressure Elevation and Autonomic Nervous Activity in Hypertensive Patients Using Wavelet Transform of Heart Rate Variability
- PJ-042 Pivotal Roles of CYLD (cylindromatosis) as a Deubiquitinating Enzyme in Vasculature(Atherosclerosis, basic(05)(IHD),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- PJ-329 Prevalence and Severity of Echocardiographic Left Ventricular Hypertrophy in Patients with Type A Versus Type B Acute Aortic Dissection(Cardiovascular surgery/CABG-2, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- PJ-688 The Role of Heritable Connective Tissue Disorders in the Pathogenesis of Aortic Dissection at Young Onset(Peripheral circulation/Vascular disease-6, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- PJ-159 The Optimal Target Blood Pressure to Avoid Acute Oliguria in Type B Aortic Dissection(Peripheral circulation/Vascular disease(06)(H),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- OJ-114 Influence of Bystander Cardiopulmonary Resuscitation in Patients with Out-of-Hospital Cardiac Arrest in Osaka : J-Pulse 2 study(OJ19,Cardiopulmonary and Critical Care/ACLS (H),Oral Presentation (Japanese),The 73rd Annual Scientific Meeting of The J
- 1 For In-hospital Cardiac Arrest, What should We Do as Risk Management in Cardiovascular Practice(Risk Management in Cardiovascular Practice,Symposium 21 (SY-21) (H),The 73rd Annual Scientific Meeting of The Japanese Circulation Society)
- PJ-708 Postchallenge Hyperglycemia is an Independent Risk Factor for Left Ventricular Hypertrophy in Non-diabetic Hypertensive Patients(Hypertension, clinical(09)(H),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation S
- 6 Japanese Clinical Trial Results of Next Generation LVAS "EVAHEART"(Symposium 8 (SY-08) (M) New Strategies for Management of Severe Heart Failure with New Devices and Surgery,Special Program,The 72nd Annual Scientific Meeting of the Japanese Circulation
- OE-250 Long and Short Term Effects of Drug-Eluting Stents on Coronary Arterial Healing in Humans(Coronary revascularization, PCI(02)(IHD),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- OJ-037 Long-term Clinical Outcome of Supervised Exercise Rehabilitation in Patients with Peripheral Arterial Diseases(Exercise test/Cardiac rehabilitation-2, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Propagation Properties of Laser-induced Streamer Corona in Atmospheric Air under Positive DC Voltages
- Gene Polymorphism of Myospryn (Cardiomyopathy-Associated 5) Is Associated with Left Ventricular Wall Thickness in Patients with Hypertension
- Genetic Polymorphisms of L-Type Calcium Channel α1c and α1D Subunit Genes are Associated With Sensitivity to the Antihypertensive Effects of L-Type Dihydropyridine Calcium-Channel Blockers
- PJ-505 Differences in Clinical Profiles of Patients with Thoracic vs Abdominal Aortic Aneurysms(Cardiovascular surgery/CABG-2 (IHD) PJ85,Poster Session (Japanese),The 70th Anniversary Annual Scientific Meeting of the Japanese Circulation Society)
- PJ-503 Increased FDP is an Independent Predictor of Adverse Late Outcomes in Patients with Acute Type B Aortic Dissection(Cardiovascular surgery/CABG-2 (IHD) PJ85,Poster Session (Japanese),The 70th Anniversary Annual Scientific Meeting of the Japanese Cir
- 1 Beyond lowering blood pressure effect of nifedipine retard : Nifedipine retard prevents hospitalization for angina pectoris better than angiotensin-converting enzyme inhibitors in hypertensive Japanese patients with a history of myocardial infarction (J
- PE-475 The Gender Difference of In-Hospital Mortality among Patients with Acute Myocardial Infarction in Japan(PE080,ACS/AMI (Clinical/Pathophysiology/Treatment/Basic), Angina Pectoris (Clinical) (IHD),Poster Session (English),The 73rd Annual Scientific M
- PJ-579 The Longer Pre-hospital Time Delay Resulted in Worse Prognosis in the Patients with Acute Myocardial Infarction from a Registry Database(Acute myocardial infarction, clinical(diagnosis/treatment)(11)(IHD),Poster Session(Japanese),The 72nd Annual Sc
- Xanthogranulomatous cystitis
- PJ-369 Citizen's Attitudes toward CPR and AED Use(Preventive medicine/Epidemiology/Education(06)(H),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- Unstable Angina and Non-ST Elevation Acute Coronary Syndrome : Epidemiology and Current Management in Japan (Japan Multicenter Investigation for Cardiovascular Disease-D (JMIC-D) Committee)
- PE-062 Zyxin Progresses Epithelial-Mesenchymal Transition under the Control of Twist1 and Contributes to Endocardial Morphogenesis(PE011,Congenital Heart Disease (M),Poster Session (English),The 73rd Annual Scientific Meeting of The Japanese Circulation S
- OJ-208 Which Blood Pressure is the Most Powerful Predictor of Hypertensive Multiple Organ Damages?(Hypertension, clinical(03)(H),Oral Presentation (Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- Effect of Early Nephrology Referral on the Initiation of Hemodialysis and Survival in Patients With Chronic Kidney Disease and Cardiovascular Diseases
- Bodyweight change during the first 5 days of chemotherapy as an indicator of cisplatin renal toxicity
- 3 Functional Analysis of Novel Antimicrobial Peptide, AG (Angiogenic Peptide)-30, with Angiongenic Property, toward Clinical Application(The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- OJ-160 Effect of Nifekalant for Out-of-Hospital Shock-Resistant Ventricular Fibrillation : J-PULSE 2 Nifekalant Multicenter Registry(Emergency care-2, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Problems with Registration-Directed Clinical Trials for Lung Cancer in Japan
- PE-275 A Novel Strategy of the Gene Therapy for PAD Using Small RNA Interference of Cold Shock Domain Protein A(PE046,Atherosclerosis (Basic, Clinical/Diagnosis) (IHD),Poster Session (English),The 73rd Annual Scientific Meeting of The Japanese Circulation
- 2 Estrogen Decreases the Activation of RANK-RANKL System in Vascular Calcification(Young Investigator's Award for International Students Finalists Lecture (YIA International),The 73rd Annual Scientific Meeting of The Japanese Circulation Society)
- PJ-250 Cold shock domain protein A, novel regulator of angiogenesis in heart.(Coronary circulation, basic/clinical(03)(IHD),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- OE-185 Topical application of novel angiogenic peptide, AG-30, in wound healing model(Growth factor/Cytokine(01)(H),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- OE-040 FHL-2 Expresses in Endothelial Cell and Suppresses VEGF-induced Angiogenesis Via Sphingosine Kinase-1(Arrhythmia, diagnosis/Pathophysiology/EPS(01)(A),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society
- OJ-195 Pivotal Roles of Deubiquitinating Enzymes UCHL1, HAUSP, and CYLD in Vasculature as an Anti-proliferative and Anti-inflammatory Effect(Atherosclerosis, basic-3, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- Polymorphisms in Vitamin K-Dependent γ-Carboxylation-Related Genes Influence Interindividual Variability in Plasma Protein C and Protein S Activities in the General Population
- Adipose Tissue-Derived Stromal Cells as a Novel Option for Regenerative Cell Therapy
- PJ-752 A Novel Model of Vasculogenesis From ES Cells for Vascular Research and Regenerative Medicine(Development and differentiation-4 (M) PJ129,Poster Session (Japanese),The 70th Anniversary Annual Scientific Meeting of the Japanese Circulation Society)
- PJ-175 Predictors of Mortality in Patients with Acute Myocardial Infarction due to Left Main Coronary Artery Occlusion(Acute myocardial infarction, clinical (diagnosis/treatment)-9, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- PJ-228 Reverse White-coat Hypertension as an Independent Risk for Carotid Atherosclerosis in Treated Hypertensive Patients(Hypertension, clinical-9 (H) PJ38,Poster Session (Japanese),The 70th Anniversary Annual Scientific Meeting of the Japanese Circulati
- PE-340 International Comparison of Clinical Use of Inotrope and Vasodilator Therapy for Acute Decompensated Heart Failure(Heart failure, clinical(10)(M),Poster Session(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- Photochemical Behavior of Indane-1, 2, 3-trione in Degassed Alcoholic Solutions : Formation of 3-Substituted Phthalides
- Patterns of failure and influence of potential prognostic factors after surgery in transitional cell carcinoma of the upper urinary tract
- Asymmetric Transfer Hydrogenation Catalyzed by Diamine - Iridium(I)Complexes
- Genetic Polymorphisms of Copper- and Platinum Drug-efflux Transporters ATP7A and ATP7B in Japanese Cancer Patients
- Phase I study of TLR9 agonist PF-3512676 in combination with carboplatin and paclitaxel in patients with advanced non-small-cell lung cancer
- Report From J-PULSE Multicenter Registry of Patients With Shock-Resistant Out-of-Hospital Cardiac Arrest Treated With Nifekalant Hydrochloride
- Photolysis of 1,2-Naphthoquinone in Oxygen-Doped Argon Matrix at Low Temperature
- Photolysis of Indan-1,2-dione Derivatives in Oxygen-Doped Argon Matrix at Low Temperature
- 1- and 3-Nitreno-2-naphthylcarbenes : A Combined Experimental and Computational Study
- A Raman Spectroscopic Study of Merocyanine Aggregates of a ^N-Isotopomer of 6-Nitro-1', 3', 3'-trimethylspiro[2H-1-benzopyran-2, 2'-indoline]. A Direct Evidence for the Association through the NO_2-Bridges
- The counterregulating role of ACE2 and ACE2-mediated angiotensin 1-7 signaling against angiotensin II stimulation in vascular cells
- Inorganic polyphosphate differentiates human mesenchymal stem cells into osteoblastic cells
- A Tris(carbene) Constructed with Stable Triplet Carbene Units
- Report From the Japanese Registry of CPR for In-Hospital Cardiac Arrest (J-RCPR)
- Impact of Therapeutic Hypothermia in the Treatment of Patients With Out-of-Hospital Cardiac Arrest From the J-PULSE-HYPO Study Registry
- Innovator and generic cisplatin formulations : Comparison of renal toxicity
- Cilnidipine, but not amlodipine, ameliorates osteoporosis in ovariectomized hypertensive rats through inhibition of the N-type calcium channel
- Transient receptor potential A1 receptor-mediated neural cross-talk and afferent sensitization induced by oxidative stress : Implication for the pathogenesis of interstitial cystitis/bladder pain syndrome
- The Condensation of Acetonitrile with Formaldehyde
- Base-induced oxygenation and chemiluminescence of 10-methylacridinium and 1-methylquinolinium salts in dimethyl sulfoxide.
- Effect of aryl substituents on 2-aryl-1,4,5,6,7,7-hexachloronorbornadiene-quadricyclane reversible isomerization.
- Photooxygenation reaction and chemiluminescence of (arylmethylenehydrazono)triphenylphosphoranes. Possible generation of phospha-1,2-dioxetanes.
- A convenient one-pot synthesis of acenaphthenequinones from 1-acenaphthenones by NBS-DMSO oxidation.
- Mechanism of the photochemical and thermal Wolff rearrangement of 2-diazo-1,3-dicarbonyl compounds.
- Temperature and isotope effects in the reactions of phenylcarbene with acetone.
- Photosensitized desulfurization of heterocyclic thioketones and its accompanied chemiluminescence.
- Photoinduced alcoholysis of trihaloacetyl group.
- Hydrogenation of diphenylethyne catalyzed by PdCl2 in CH2Cl2 and polyethylene glycol.
- Carbene in rigid matrix. XI. Temperature and matrix effect on phenylcarbene processes in ether and amine.
- Photoinduced alcoholysis of .ALPHA.,.ALPHA.,.ALPHA.-tribromoacetophenone to benzoylformate.
- Photochemical reactions in polyethylene glycol. 2. Photo-induced nucleophilic substitution of dimethoxybenzenes in the presence of polyethylene glycol.
- Photochemical Type II Elimination of Diisobutyl Trichloromethylphosphonate
- A single-step synthesis of 2-substituted 2-thiazolines.
- Photolysis of Methyl Benzenesulfonate in Methanol
- The photochemical debromination of bromocyclopropane in the presence of amine.
- The low-temperature photolysis of diazo compounds. The utility of tertiary alcohol in matrix studies of carbene chemistry.
- Flash vacuum pyrolysis of 5-diazodibenzo(ad)cycloheptene. Some insights into aromatic carbene-arylcarbene rearrangement.
- Effects of aryl substituents on electron-transfer-mediated photochemical addition of alcohol to 1,1,2-triarylcyclopropanes.