Photolysis of Methyl Benzenesulfonate in Methanol
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概要
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The irradiation of methyl benzenesulfonate (<B>1</B>) in methanol undergoes a photolysis (Φ<SUB>disapp</SUB>=0.07±0.005) leading to benzene (5–34%), biphenyl (9–15%), and anisole (trace), in place of a photo-addition of methanol to give bicyclohexene derivatives. The rate of desulfonation of <B>1</B> is only slightly affected by triethylamine. Stern-Volmer quenching by piperylene occurs and the results suggest a significant singlet participation in this photolysis.
- 公益社団法人 日本化学会の論文
著者
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Izawa Yasuji
Department Of Applied Chemistry Aichi Institute Of Technology
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Kuromiya Naoki
Department of Industrial Chemistry, Faculty of Engineering, Mie University
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