Carbene in rigid matrix. XI. Temperature and matrix effect on phenylcarbene processes in ether and amine.
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概要
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Product distributions from reactions of phenylcarbene with diethyl or diisopropyl ether or diethylamine were found to be highly dependent on reaction temperature. As temperature decreases, the C–O displacement reaction and N–H insertion are decreased. Concomitantly, primary C–H insertion products markedly increase especially at lower matrix temperatures.
- 公益社団法人 日本化学会の論文
著者
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Izawa Yasuji
Department Of Applied Chemistry Aichi Institute Of Technology
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Tomioka Hideo
Department Of Applied Chemistry Aichi Institute Of Technology
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Suzuki Shinji
Department Of Aeronautics And Astronautics The University Of Tokyo
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