The photochemical debromination of bromocyclopropane in the presence of amine.
スポンサーリンク
概要
- 論文の詳細を見る
The irradiation of bromoarylcyclopropanes (<B>1</B>) in the presence of tertiary amine resulted in the formation of the debrominated cyclopropanes as a mixture of geometrical isomers, whose ratios were essentially similar regardless of the stereochemistry of the bromide. The reactions were not, however, observed in the absence of amine. The results are interpreted as indicating that the reactions proceed through an initial single-electron transfer to the excited <B>1</B>, followed by debromination and hydrogen-abstraction.
- 公益社団法人 日本化学会の論文
著者
-
Tomioka Hideo
Department Of Applied Chemistry Aichi Institute Of Technology
-
Inoue Osamu
Department Of Clinical And Laboratory Medicine Faculty Of Medicine University Of Yamanashi
-
Inoue Osamu
Department of Industrial Chemistry, Faculty of Engineering, Mie University
-
Inoue Osamu
Department of Chemistry, Faculty of Science, Toyama University
関連論文
- Molecular analysis of the pathophysiological binding of the platelet aggregation-inducing factor podoplanin to the C-type lectin-like receptor CLEC-2
- -0399- INTRAVASCULAR ULTRASOUND IMAGING IN CHILDREN AFTER KAWASAKI DISEASE : ASSESSMENT OF CORONARY & SYSTEMIC ARTERY, AND APPLICATION TO INTERVENTION.(PROCEEDINGS OF THE 59th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY)
- -0394- STENTING OF THE DUCTUS ARTERIOSUS IN NEWBORN PIGLETS : COMPARISON OF EXPERIMENTAL EFFICACY BETWEEN PALMATZ-SCHATZ AND GIANTURCO-ROUBIN STENTS(PROCEEDINGS OF THE 59th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY)
- Evaluation of Pulmonary Arterial Pathology in Congenital Heart Disease : In Vitro Study Using Intravascular Ultrasound Imaging
- IMPROVEMENT OF LEFT VENTRICULAR PERFORMANCE AFTER MYOCARDIAL INFARCTION IN PATIENTS WITH KAWASAKI DISEASE
- MYOCARDIAL ISCHEMIA IN KAWASAKI DISEASE : EVALUATION BY DIPYRIDAMOLE STRESS THALLIUM-201(Tl-201)MYOCARDIAL IMAGING
- INTRAVASCULAR ULTRASOUND IMAGING OF CORONARY ARTERY IN CHILDREN AFTER KAWASAKI DISEASE:ASSESSMENT OF WALL MORPHOLOGY IN REGRESSED CORONARY ANEURYSMS AND ANGIOGRAPHICALLY NORMAL CORONARY ARTERY
- -0124-SUDDEN DEATH AFTER SURGERY IN PATIENTS WITH CONGENITAL HEART DISEASE
- MITRAL VALVE PROLAPSE SYNDROME (MVP) IN CHILDHOOD : CHANGE OF INCIDENCE AND CLINICAL MANIFESTATIONS BY AGE : Valvular Heart Disease : 53 Annual Scientific Meeting, Japanese Circulation Society
- TERM FOLLOW-UP OF CORONARY ARTERIAL LESIONS IN KAWASAKI DISEASE : SERIAL ANGIOGRAPHIC STUDY : Congenital Heart Disease, Kawasaki Disease : 53 Annual Scientific Meeting, Japanese Circulation Society
- LONG TERM OF EVALUATION OF HEMODYNAMIC FINDINGS AND MORPHOLOGIC CHANGES OF RIGHT VENTRICULAR OUTFLOW TRACT AFTER BALLOON PULMONARY VALVULOPLASTY : Congenital Heart Disease, Kawasaki Disease : 53 Annual Scientific Meeting, Japanese Circulation Society
- -156- INCIDENCE OF MITRAL VALVE PROLAPSE IN NEONATES, INFANTS AND CHILDREN : A TWODIMENSIONAL ECHOCARDIOGRAPHIC STUDY OF 2285 NORMAL SUBJECTS : Myocardial Infarction, Valvular Heart Disease : FREE COMMUNICATIONS(I) : PROCEEDINGS OF THE 51th ANNUAL SCIENTI
- Enhancement of the relative uptake of F-FDG in mouse fibrosarcoma by rolipram
- Ionic interaction of [^C]-N, α-dimethylbenzylamine (DMBA) in rodent brain
- Effect of sabcomeline on muscarinic and dopamine receptor binding in intact mouse brain
- FATE OF CORONARY ANEURYSM IN KAWASAKI DISEASE : ANALYSIS OF FACTORS EFFECTED ON THE PROGRESSION TO CARDIOVASCULAR SEQUALAE : Congenital Heart Disease, Kawasaki Disease : IV : 48 Annual Scientific Meeting, Japanese Circulation Society
- Photolysis of 1,2-Naphthoquinone in Oxygen-Doped Argon Matrix at Low Temperature
- Photolysis of Indan-1,2-dione Derivatives in Oxygen-Doped Argon Matrix at Low Temperature
- 1- and 3-Nitreno-2-naphthylcarbenes : A Combined Experimental and Computational Study
- Changes in Histological Construction and Decrease in 3H-QNB Binding in the Rat Brain after Prenatal X-irradiation
- A Raman Spectroscopic Study of Merocyanine Aggregates of a ^N-Isotopomer of 6-Nitro-1', 3', 3'-trimethylspiro[2H-1-benzopyran-2, 2'-indoline]. A Direct Evidence for the Association through the NO_2-Bridges
- Distinct different intra-tumor distribution of FDG between early phase and late phase in mouse fibrosarcoma
- A Tris(carbene) Constructed with Stable Triplet Carbene Units
- Phase Relations and Equilibrium Oxygen Partial Pressures in Iron-Titanium-Oxygen System at 1373 K
- INTERMEDIATE-TERM EFFECTIVENESS AND PROBLEMS OF BALLOON VALVULOPLASTY FOR CONGENITAL VALVULAR AORTIC STENOSIS
- Experimental Simulation on the Beam Heating Effects in Ion Implantation Techniques
- Laminin Stimulates Spreading of Platelets Through Integrin α_6β_1-dependent Activation of GPVI
- Fetal echocardiography: Recognition and intrauterine treatment of fetal cardiac problems and prenatal diagnosis of congenital heart disease.
- Hemodynamic evaluation and morphological changes of right ventricular out-flow tract and pulmonary valve after balloon pulmonary valvuloplasty.
- The synthesis of racemic formannoxin, anodendroic acid, and 5-acetyl-2-(1-(hydroxymethyl)vinyl)2,3-dihydrobenzofuran.
- Effect of aryl substituents on 2-aryl-1,4,5,6,7,7-hexachloronorbornadiene-quadricyclane reversible isomerization.
- Mechanism of the photochemical and thermal Wolff rearrangement of 2-diazo-1,3-dicarbonyl compounds.
- Temperature and isotope effects in the reactions of phenylcarbene with acetone.
- Photoinduced alcoholysis of trihaloacetyl group.
- Carbene in rigid matrix. XI. Temperature and matrix effect on phenylcarbene processes in ether and amine.
- Photoinduced alcoholysis of .ALPHA.,.ALPHA.,.ALPHA.-tribromoacetophenone to benzoylformate.
- The photochemical debromination of bromocyclopropane in the presence of amine.
- Cardiac rhabdomyoma in a newborn infant. The diagnostic role of echocardiography.:The Diagnostic Role of Echocardiography
- Valvular heart disease in Kawasaki syndrome. Incidence and natural history.:Incidence and Natural History
- The low-temperature photolysis of diazo compounds. The utility of tertiary alcohol in matrix studies of carbene chemistry.
- Polymer effects under pressure. III. Hydrolysis of normal alkyl acetate catalyzed by dodecyl hydrogensulfate micelle.
- Flash vacuum pyrolysis of 5-diazodibenzo(ad)cycloheptene. Some insights into aromatic carbene-arylcarbene rearrangement.
- A study on the optimal dose of aspirin therapy in Kawasaki disease. Clinical evaluation and arachidonic acid metabolism.:Clinical Evaluation and Arachidonic acid Metabolism
- Effects of aryl substituents on electron-transfer-mediated photochemical addition of alcohol to 1,1,2-triarylcyclopropanes.