N-Hydroxy amides. IV Synthesis and properties of a trihydroxamic acid anilide as a model for ferrioxamines.
スポンサーリンク
概要
- 論文の詳細を見る
A trihydroxamic acid having a 6-aminohexanoyl–3-(hydroxyamino)propanoyl sequence has been synthesized in a stepwise manner, starting with glycinanilide. The trihydroxamic acid anilide bears a good structural resemblance with <I>N</I>-benzoyl-deferriferrioxamine B (Benzoyl-DFB). A plot of the absorbance vs. the molar ratio of iron(III) to the hydroxamate group indicates the formation of a 1:1 intramolecular iron(III) complex for the trihydroxamic acid anilide and Benzoyl-DFB. Cyclic voltammetry also shows that the iron complexes of both compounds have similar electrochemical properties. A solid iron(III) complex was obtained when the trihydroxamic acid anilide was mixed with tris(2,4-pentanedionato)iron(III) in methanol.
- 公益社団法人 日本化学会の論文
著者
-
Shimizu Kazuyuki
Department of Applied Chemistry for Resources, Tokyo University of Agriculture and Technology
-
Nakayama Kazuyuki
Department of Applied Chemistry for Resources, Tokyo University of Agriculture and Technology
関連論文
- Metabolic Pathway Analysis of Recombinant Saccharomyces cerevisiae with a Galactose-Inducible Promoter Based on a Signal Flow Modeling Approach
- Phase II and pharmacokinetic study of thalidomide in Japanese patients with relapsed/refractory multiple myeloma
- Quantitative Analysis of Intracellular Metabolic Fluxes Using GC-MS and Two-Dimensional NMR Spectroscopy
- Metabolic Control Analysis for Lysine Synthesis Using Corynebacterium glutamicum and Experimental Verification
- Development of a Kinetic Model for L-Lysine Biosynthesis in Corynebacterium glutamicum and Its Application to Metabolic Control Analysis
- Metabolic Flux Analysis for Efficient Pyruvate Fermentation Using Vitamin-Auxotrophic Yeast of Torulopsis glabrata
- Metabolic Flux Analysis for Biosynthesis of Poly(β-Hydroxybutyric Acid) in Alcaligenes eutrophus from Various Carbon Sources
- Efficient Production of Vitamin B_ from Propionic Acid Bacteria under Periodic Variation of Dissolved Oxygen Concentration
- Application of Artificial Neural Network and Fuzzy Control for Fed-Batch Cultivaton of Recombinant Saccharomyces cerevisiae
- Performance Improvement of Lactic Acid Fermentation by Multistage Extractive Fermentation
- Fuzzy Neural Network for the Control of High Cell Density Cultivation or Recombinant Escherichia coli
- Effect of Controlling Lactate Concentration and Periodic Change in DO Concentration on Fermentation Characteristics of a Mixed Culture of Lactobacillus delbrueckii and Ralstonia eutropha for PHB Production
- Rapid Production of Pediococcus halophilus Salt-Tolerant Cells by a Cultivation Method Employing Gradual Increases in NaCl Concentration Using a Fermentor with a Microfiltration Module
- Posttreatment M-Protein Nadir Level Is a Significant Prognostic Factor Associated with Survival in Multiple Myeloma
- Continuous Lactic Acid Production from Raw Starch in a Fermentation System Using a Reversibly Soluble-autoprecipitating Amylase and Immobilized Cells of Lactobacillus casei(Microbiology & Fermentation Industry)
- Development of Dual On-Line Analyzer and Its Application to Fed-Batch Lactic Acid Fermentation
- Adaptive On-Line Optimizing Control for Lactic Acid Fermentation
- Hodgkin's disease following extranodal marginal zone B-cell lymphoma in remission
- Targeting of Soybean-Derived Sterylglucoside Liposomes to Liver Tumors in Rat and Mouse Models
- Formulation of Liposomes with a Soybean-Derived Sterylglucoside Mixture and Cholesterol for Liver Targeting
- On-Line Control of Glucose Concentration Using An Automatic Glucose Analyzer
- Association of Liposomes Containing a Soybean-Derived Sterlyglucoside Mixture with Rat Primary Cultured Hepatocytes
- Knowledge-Based Design and Operation of Bioprocess Systems
- Proteome Analysis of a Temperature-Inducible Recombinant Escherichia coli for Poly-β-Hydroxybutyrate Production
- An Integrated Metabolic Pathway Analysis Based on Metabolic Signal Flow Diagram and Cellular Energetics for Saccharomyces cerevisiae
- 571 Computer-mediated addition of fresh medium in continuous culture of Zymomonas mobilis by the monitoring of weight changes
- Hepatic Branched-Chain α-Keto Acid Dehydrogenase Complex in Female Rats : Activation by Exercise and Starvation
- Application of Dual-Energy K-Edge Subtraction Imaging to Assessment of Heat Treatments in Al-Cu Alloys
- Modification of Metabolic Pathways of Saccharomyces cerevisiae by the Expression of Lactate Dehydrogenase and Deletion of Pyruvate Decarboxylase Genes for the Lactic Acid Fermentation at Low pH Value
- Effect of Modifying Metabolic Network on Poly-3-Hydroxybutyrate Biosynthesis in Recombinant Escherichia coli
- Efficient Production of Gene Products by Repeated Fed-Batch Fermentation Using Multiple Fermentors
- Solvent extraction of plant pigments from leaf protein concentrate.
- N-Hydroxy amides. IV Synthesis and properties of a trihydroxamic acid anilide as a model for ferrioxamines.
- N-hydroxy amides. I. Synthesis of N-benzyloxy and N-hydroxy peptides via polymerization of N-benzyloxy DL-.ALPHA.-amino acid N-carboxy anhydrides.
- Comparison of control techniques for baker's yeast culture using an automatic glucose analyzer.
- N-hydroxy amides. III. Active esters of polystyrene-bound 1-hydroxy-2-pyrrolidinone and their use in peptide synthesis.
- On the expansion of the transfer function for the model reduction of stage systems.
- Singular value analysis for the Robust control system design of distillation systems.
- Control of cell and lactate concentration in a hollow-fiber bioreactor for lactic acid fermentation.