A new method for the synthesis of 3,5-disubstituted 2(5H)-furanones. Synthesis of (.+-.)-acarenoic acid.
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概要
- 論文の詳細を見る
Heating of 3,5-disubstituted 4-bromo-3-methoxycarbonyldihydro-2(3<I>H</I>)-furanones with NaI in 3-pentanone gave 3,5-disubstituted 2(5<I>H</I>)-furanones in 55.8–93.3% isolated yields. A total synthesis of (±)-acarenoic acid was established in 33% overall yield via 4 steps.
- 公益社団法人 日本化学会の論文
著者
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Tsuboi Sadao
Department Of Applied Chemistry Faculty Of Engineering Okayama University
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Takeda Akira
Department Of Gastroenterology Osaka General Medical Center
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Wada Hiroshi
Department Of Bioengineering And Robotics Tohoku University
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Muranaka Koichi
Department of Synthetic Chemistry, School of Engineering, Okayama University
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Takeda Akira
Department of Applied Chemistry, Faculty of Engineering, Okayama University
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