Electrolyses of 2,2-Dichloro-3-phenylcyclopropanecarboxylic Acids in Hydroxylic Solvents with a Platinum Anode
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概要
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Electrolysis of 2,2-dichloro-3-phenylcyclopropanecarboxylic acid (<B>1a</B>) in hydroxylic solvents such as methanol and acetic acid, or in aqueous methanol with acetic acid in excess, was carried out with a platinum anode. Solvolysis rather than coupling was found to occur yielding 3,3-dichloro-1-phenylallyl methyl ether (<B>4a</B>) or 3,3-dichloro-1-phenylallyl acetate (<B>5a</B>), or both, depending on the solvent. Electrolysis of 2,2-dichloro-3-methyl-3-phenylcyclopropanecarboxylic acid (<B>1b</B>) in aqueous methanol gave ether <B>4b</B>. Structural characterization of the products was also discussed.
- 公益社団法人 日本化学会の論文
著者
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Murakami Yasuo
Department Of Anesthesiology Saitama Medical School
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Takeda Akira
Department Of Gastroenterology Osaka General Medical Center
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Wada Satosi
Department of Synthetics Chemistry, School of Engineering, Okayama University
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Murakami Yasuo
Department of Synthetics Chemistry, School of Engineering, Okayama University
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Takeda Akira
Department of Applied Chemistry, Faculty of Engineering, Okayama University
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