Asymmetric synthesis using chiral piperazine. I. Asymmetric synthesis of 2-substituted alcohol and carboxylic acid by diastereoselective alkylation of chiral diamides derived from piperazines.

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概要

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• The diastereoselective alkylation of chiral diamides derived from chiral piperazines afforded optically active alcohols and acids in moderate enantiomeric excesses (up to 68% e.e.).

• 公益社団法人 日本化学会の論文

著者

• Hayashi Hiroshi

  Department of Biomolecular Science, Faculty of Science, Toho University

• Yamada Yasuyuki

  Department Of Agricultural Chemistry Faculty Of Agriculture Kyoto University

• Soai Kenso

  Department Of Applied Chemistry Faculty Of Science Science University Of Tokyo

• Shinozaki Akihiro

  Department of Applied Chemistry, Faculty of Science, Science University of Tokyo

• Umebayashi Hideaki

  Department of Applied Chemistry, Faculty of Science, Science University of Tokyo

• Yamada Yasuyuki

  Department of Applied Chemistry, Faculty of Science, Science University of Tokyo

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