Kinetics of absorption of sulfur dioxide and nitric oxide in aqueous mixed solutions of sodium chlorite and sodium hydroxide.
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概要
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The rates of single and simultaneous absorptions of dilute SO2 and NO in aqueous mixed solutions of NaClO2 and NaOH were measured at 25°C using a stirred vessel with a plain gas-liquid interface. In the SO2-NaClO2 system, the absorption rate exceeded the gas-film controlled rate, which implies the possibility of gas-phase oxidation of SO2 due to the evolved C1O2. In the SO2-(NaClO2+NaOH) system, the absorption rate agreed with that under gas-film controlled conditions. In the (SO2+NO)-(NaClO2+NaOH) system, the reduction of the NO absorption rate in the presence of SO2 substantially exceeded that evaluated through the decrease in interfacial concentration of NaClO2 and NaOH due to surface reaction with coexisting SO2. The rate of absorption of SO2 exceeded the gas-film controlled rate. The decomposition of NaClO2 proceeds to a greater degree during simultaneous absorption than the single absorption of SO2.
- 公益社団法人 化学工学会の論文
著者
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Sada Eizo
Department Of Chemical Engineering Faculty Of Engineering Kyoto Univeristy
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Kondo Takashi
Department Of Agricultural Chemistry The University Of Tokyo
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YAMANAKA YASUO
Department of Chemical Engineering, Nagoya University
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KUMAZAWA HIDEHIRO
Department of Chemical Engineering, Faculty of Engineen Nagoya University
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SADA EIZO
Department of Chemical Engineering, Nagoya University
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KUDO ICHIBEI
Department of Chemical Engineering, Nagoya University
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