CLAY COLUMN CHROMATOGRAPHY FOR OPTICAL RESOLUTION : PARTIAL RESOLUTION OF 1,1'-BINAPHTHOL ON OPTICALLY ACTIVE [Co (phen)_<3-x> (am)_x]^<n+>-MONTMORILLONITE COLUMNS

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概要

• 論文の詳細を見る

• High-pressure liquid chromatography columns were packed with silica gel coated with montmorillonite ion-exchanged by cationic complex, [Co (phen)_<3-x> (am)_x]^<n+> (phen=1,10-phenanthroline, am = isoleucinato or prolinato). A racemic compound of 1,1'-binaphthol was partially resolved on the above columns using pure water as an eluting solvent. The chiral discrimination is probably attributable to the absolute configuration of amino acid ligand, but not of the complex itself.

• 日本粘土学会の論文

著者

• Nakamura Yuji

  Department Of Materials Engineering Graduate School Of Engineering The University Of Tokyo:crest Jap

• Yamagishi Akihiko

  Department Of Chemistry College Of Arts And Sciences The University Of Tokyo

• IWANOTO TOSCHITAKE

  Department of Chemistry, College of Arts and Sciences, The University of Tokyo

• Nakamura Yuji

  Department Of Chemistry College Of Arts And Sciences The University Of Tokyo

• Nakamura Yuji

  Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University

• Iwanoto Toschitake

  Department Of Chemistry College Of Arts And Sciences The University Of Tokyo

• YAMAGISHI Akihiko

  Department of Applied Molecular Biology, Tokyo University of Pharmacy and Life Sciences

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