Substitution reactions of (acetonitrile)chlorobis(triphenylphosphine)rhodium(I) in benzene.
スポンサーリンク
概要
- 論文の詳細を見る
The kinetics of the substitution reactions of RhCl(NCCH<SUB>3</SUB>)(PPh<SUB>3</SUB>)<SUB>2</SUB> in benzene was studied at 20 °C by the stopped-flow method under anaerobic conditions. The following mechanism was proposed:<BR>(<U>Remark: Graphics omitted.</U>)
- 公益社団法人 日本化学会の論文
著者
-
Yamagishi Akihiko
Department Of Chemistry College Of Arts And Sciences The University Of Tokyo
-
FUJIMOTO Masatoshi
Department of Chemistry, Faculty of Science, Hokkaido University
-
Ohtani Yoshimi
Department of Chemistry, Faculty of Science, Hokkaido University
関連論文
- ANALYSES OF COMPLETE NUCLEOTIDE SEQUENCES OF SOLITARY ENTOPROCT MITOCHONDRIAL GENOMES(Taxonomy and Systematics,Abstracts of papers presented at the 76^ Annual Meeting of the Zoological Society of Japan)
- 1P075 中立変異の蓄積を減らした祖先型タンパク質間の比較による配列-安定性相関の解析(蛋白質-物性(安定性,折れたたみなど),第48回日本生物物理学会年会)
- The Effects of Mutations at Position 253 on the Thermostability of the Bacillus subtilis 3-Isopropylmalate Dehydrogenase Subunit Interface
- Childhood psoriasis associated with Turner syndrome
- Investigation of cultivable microorganisms in the stratosphere collected by using a balloon in 2005
- In Situ Ore Formation Experiment : Amino Acids and Amino Sugars Trapped in Artificial Chimneys on Deep-Sea Hydrothermal Systems at Suiyo Seamount, Izu-Bonin Arc, Pacific Ocean
- Assessing Panspermia Hypothesis by Microorganisms Collected from The High Altitude Atmosphere
- UV-resistant bacteria isolated from upper troposphere and lower stratosphere
- RACEMIC ADSORPTION OF TRIS (1, 10-PHENANTHROLINE)RUTHENIUM (II) : ONTO A MICA SURFACE
- 1P144 Hyperthermophilic translation system in the common ancestor : Analysis of ancestral mutants of GlyRS of the Thermus thermophilus(4. Protein engineering,Poster Session,Abstract,Meeting Program of EABS & BSJ 2006)
- Organics in chimneys and water samples from deep-sea hydrothermal systems : Implications for sub-vent biosphere
- Association of Micropenis with Pro185Ala Polymorphism of the Gene for Aryl Hydrocarbon Receptor Repressor Involved in Dioxin Signaling
- Ancestral Residues Stabilizing 3-Isopropylmalate Dehydrogenase of an Extreme Thermophile : Experimental Evidence Supporting the Thermophilic Common Ancestor Hypothesis
- Cold Adaptation of the Thermophilic Enzyme 3-Isopropylmalate Dehydrogenase
- Screening of a Mutant Plasmid with High Expression Efficiency of GC-Rich leuB Gene of an Extreme Thermophile, Thermus thermophilus, in Escherichia coli
- Fluorescence induction in chloroplasts isolated from the green alga Bryopsis maxima III. A fluorescence transient indicating proton gradient across the thylakoid membrane
- Fluorescence induction in chloroplasts isolated from the green alga, Bryopsis maxima I. Occurrence of the complete Kautsky effect in Bryopsis chloroplasts
- Endosymbiotic Methanobrevibacter species Living in Symbiotic Protists of the Termite Reticulitermes speratus Detected by Fluorescent In Situ Hybridization
- Continuous Cell-free Protein Synthesis Directed by Messenger DNA and Catalyzed by Extract of Thermus thermophilus HB27(Biochemistry & Molecular Biology)
- Phylogenetic Analysis of Symbiotic Archaea Living in the Gut of Xylophagous Cockroaches
- Polypeptide Synthesis Directed by DNA as a Messenger in Cell-Free Polypeptide Synthesis by Extreme Thermophiles, Thermus thermophilus HB27 and Sulfolobus tokodaii Strain 7
- Methanogenic Symbionts and the Locality of their Host Lower Termites
- ELECTRON SPIN RESONANCE STUDIES ON TRIS (1,10-PHENANTHROLINE) COPPER (II) ADSORBED BY HECTORITE AND SAPONITE
- Japan Astrobiology Mars Project (JAMP) : Search for Microbes on The Mars Surface with Special Interest in Methane-Oxidizing Bacteria
- Enantioselective Sensing by Luminescence from Cyclometalated Iridium(III) Complexes Adsorbed on a Colloidal Saponite Clay
- Scanning Atom Probe Study of Dissociation of Organic Molecules on Titanium Oxide
- Orotate Phosphoribosyltransferase from Thermus thermophilus: Overexpression in Escherichia coli, Purification and Characterization
- Purification and Characterization of Geranylgeranylglyceryl Phosphate Synthase from a Thermoacidophilic Archaeon, Thermoplasma acidophilum
- Comparison of Vibrational Circular Dichroism between the Langmuir-Blodgett Films and Gels of 12-Hydroxyoctadecanoic Acid
- Mimicking the evolution of a thermally stable monomeric four-helix bundle by fusion of four identical single-helix peptides
- Different Magnetic Properties for Diastereomers of Alkoxide-bridged (β-Diketonato)ruthenium(III) Binuclear Complexes
- Microbial ecosystem in marine hydrothermal system in the early and present earth (特集 2010年学術講演会におけるシンポジウム 海底熱水系と生命の起原)
- Application of the ΔΛ isomerism of octahedral metal complexes as a chiral source in photochemistry
- CLAY COLUMN CHROMATOGRAPHY FOR OPTICAL RESOLUTION : PARTIAL RESOLUTION OF 1,1'-BINAPHTHOL ON OPTICALLY ACTIVE [Co (phen)_ (am)_x]^-MONTMORILLONITE COLUMNS
- THERMOPHILES AND EARLY EVOLUTION OF LIFE(Coevolution of Earth and Life, International Symposium on Origins of Life and Astrobiology)
- Capture of Radioactive Nuclear Wastes from Sea Water by Use of Clay Minerals
- Tanpopo Cosmic Dust Collector : Silica Aerogel Production and Bacterial DNA Contamination Analysis
- XRD and HRTEM Evidence for Fixation of Cesium Ions in Vermiculite Clay
- Twenty-Five Millisecond Resolution Time-Resolved X-Ray Absorption Spectroscopy in Dispersive Mode
- A Microscopic Model for Helical Twisting Power by the Optical Isomers of an Octahedral Metal Complex
- Mechanism of the reactions of oxomolybdenum(V) tetraphenylporphyrin complex with alcohols in the presence of superoxide.
- Thermochromism of metal chelates with triphenylmethane complexons in aqueous solutions. III. Copper(II)-methylthymol blue and -methylxylenol blue systems.
- Proton magnetic resonance studies of 4-(2-pyridylazo)resorcinol (PAR) and its cobalt(III) complexes.
- Thermochromism of metal chelates with triphenylmethane complexons in aqueous solutions. II. Inhibitive effects of the protolysis of aqua Cu2+ ion on the thermochromism of Cu(II)-xylenol orange chelate.
- Purification of methylthymol blue and methylxylenol blue by high-performance liquid chromatography.
- Spin-state equilibria of the nickel(II) complexes of 2,12-dimethyl-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),2,11,13,15-pentaene analogs in water.
- Dehydration associated with high-spin to low-spin conversion of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-nickel(II) halide dihydrate.
- Rate and Mechanism of the Complex Formation of Thallium(III) with 4-(2-Pyridylazo)resorcinol (PAR) in Aqueous Solution
- Kinetics of the Substitution of Acetonitrile in (Acetonitrile)chlorobis(triphenylphosphine)rhodium(I) by Triphenylphosphine
- The rates of the hydrogenation of the coordinated styrene and acrylonitrile in a rhodium-olefin complex [RhClH2(ol)(PPh3)2].
- A note on the rates of complex formation of indium(III) with murexide and the decomposition of murexide in the presence of indium(III).
- Kinetics of the oxidative addition of hydrogen to chloro(acrylonitrile)-bis(triphenylphosphine)rhodium(I) in benzene.
- Substitution reactions of (acetonitrile)chlorobis(triphenylphosphine)rhodium(I) in benzene.
- The effect of halo ligand on the rate of hydrogenation of coordinated olefin in dihydrido-olefin complexes RhXH2(ol)(PPh3)2(X=Cl, Br, I).
- Kinetic study on dimerization of chlorotris(triphenylphosphine)rhodium(I) in benzene.
- Thermochromism of metal chelates with triphenylmethane complexons in aqueous solutions. I. Copper(II)-xylenol orange system.
- Kinetic Study of the Formation and Decomposition of Amylose-iodine-iodide Complex
- Reaction of bis[1-(2-pyridylazo)-2-naphtholato[cobalt(III) chloride, [Co3(pan)2]Cl, with hyperoxide in dimethyl sulfoxide.
- Kinetics and Mechanisms of the Reaction of Fe(III) with Variamine Blue, [N-(p-Methoxyphenyl)phenylenediamine] in Aqueous Perchlorate Media
- Kinetics and Mechanisms of the Reactions of Ce(IV) and Co(III) with Variamine Blue, [N-(p-Methoxyphenyl)phenylenediamine], in Aqueous Perchlorate Media
- Reaction Rates and Mechanisms of the Formation of Gallium(III), Indium(III), and Thallium(III) Complexes with Semi-Xylenol Orange in Aqueous Solutions
- Absorption spectra of new oxomolybdenum(V) complexes of tetraphenylporphyrin with univalent ligands.
- Determination of hyperoxide in dimethyl sulfoxide by photometric titration with iodine.
- Effects of quinones on the protonation reaction of TCNQ anion radical; The role of a protonated quinone as a strong electron acceptor.
- Formation of the N,N-bidentate chelates of 2-(2-pyridylazo)phenolic ligands with nickel(II) in nonaqueous solvents.
- Kinetic study of oxidative addition and replacement reactions of chlorotris(triphenylphosphine)rhodium(I) in benzene.
- Reaction Rates in the Monomer-Dimer Equilibrium of TCNQ Anion Radicals as Studied by the Temperature-Jump Method
- The Role of Solvents in the Dimerization of the 2,3-Dichloro-5,6-dicyano-p-benzoquinone Anion Radical
- Rate of protonation of TCNQ anion radical in water.
- Electron transfer reaction between .DELTA.2,2'-bi-1,3-dithiole (TTF) and 7,7,8,8-tetracyanoquinodimethane (TCNQ). Electron donating property of TTF.
- Oxidation-reduction equilibrium between cation radicals. An approach to determine ionization potentials of electron donor molecules.
- The Temperature Dependence of Hole Injection into Anthracene Crystals
- Solvation effects on the electron-transfer reaction of TCNQ anion radical and 2,3-dichloro-5,6-dicyano-p-benzoquinone.
- Kinetics of the Aquation of Iron(III) Monophenolate Complexes; Absence of the Acid-dependent Path
- Elemental dissolution of basalts with ultra-pure water at 340℃ and 40MPa in a newly developed flow-type hydrothermal apparatus
- Design of a Silica-aerogel-based Cosmic Dust Collector for the Tanpopo Mission Aboard the International Space Station