Kinetics of the Substitution of Acetonitrile in (Acetonitrile)chlorobis(triphenylphosphine)rhodium(I) by Triphenylphosphine
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概要
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The substitution of coordinated acetonitrile in (acetonitrile)chlorobis(triphenylphosphine)rhodium(I) by triphenylphosphine was studied in benzene by the stopped-flow method under anaerobic conditions. The reaction was found to proceed through both an associative and a dissociative path to yield chlorotris(triphenylphosphine)rhodium(I).
- 公益社団法人 日本化学会の論文
著者
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Yamagishi Akihiko
Department Of Chemistry College Of Arts And Sciences The University Of Tokyo
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FUJIMOTO Masatoshi
Department of Chemistry, Faculty of Science, Hokkaido University
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Ohtani Yoshimi
Department of Chemistry, Faculty of Science, Hokkaido University
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