Rate and Mechanism of the Complex Formation of Thallium(III) with 4-(2-Pyridylazo)resorcinol (PAR) in Aqueous Solution
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概要
- 論文の詳細を見る
The kinetics of complex formation of Tl(III) with PAR (LH<SUB>3</SUB><SUP>+</SUP>) was studied in aqueous solution at 25 °C, [H<SUP>+</SUP>]=0.1–1.0 mol dm<SUP>−3</SUP>, and ionic strength <I>I</I>=2.0 mol dm<SUP>−3</SUP> (NaClO<SUB>4</SUB>). The formation rate constants <I>k</I><SUB>1</SUB> and <I>k</I><SUB>2</SUB> assigned to the reactions of Tl<SUP>+3</SUP> and TlOH<SUP>2+</SUP> with LH<SUB>3</SUB><SUP>+</SUP> were determined to be 4.1×10<SUP>4</SUP> and 1.8×10<SUP>5</SUP> mol<SUP>−1</SUP> dm<SUP>3</SUP> s<SUP>−1</SUP>, respectively. The rate data were discussed in comparison with those for Tl(III)–Semi-Xylenol Orange system.
- 公益社団法人 日本化学会の論文
著者
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Imamura Taira
Department Of Chemistry Faculty Of Science Hokkaido University
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Funada Ryuichi
Department Of Cardiology Cardiovascular Institute
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FUJIMOTO Masatoshi
Department of Chemistry, Faculty of Science, Hokkaido University
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Funada Ryuichi
Department of Chemistry, Faculty of Science, Hokkaido University
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